Perfumery Material: Hedione (Luminous/Transparent Jasmine)

 Smelling hedione, I'm struck by its beautiful, limpid and luminous character which resembles the beautiful citrusy floral note of a magnolia blossom blossoming under sunny skies.
Hedione or methyl dihydrojasmonate is an aromachemical (patented as Hedione by aroma-producing company Firmenich) that is often used in composition in substitution for jasmine absolute, but also for the sake of its own fresh-citrusy and green tonality.

Hedione lacks the clotted cream density of natural jasmine, recalling much more the living vine in the warmth of summer mornings and for that reason it is considered a beautiful material that offers quite a bit in the production of fine perfumes.

Perfumer Lyn Harris, nose of the brand Miller Harris and also the independent nose behind many well-known creations not credited to her name, calls it “transparent jasmine” and attributes to it the capacity to give fizz to citrus notes much “like champagne”. (See? it’s not only aldehydes which do that!)

According to Christian Chapuis of Firmenich SA, Edouard Demole discovered methyl jasmonate in 1957, accomplished a synthesis of Hedione (from the Greek word ηδονή/hedone, meaning agreeable and pleasant) in 1958, synthesized methyl jasmonate in 1959, placed both materials under intellectual protection in 1960, and published these discoveries in 1962. "This simple timeline belies a more complex history of chemistry and creation".
First used in the classic men’s cologne Eau Sauvage, composed by Edmond Roudnitska in 1966, hedione had been isolated from jasmine absolute and went on to revolutionize men’s scents with the inclusion of a green floral note. Eau Sauvage was so successful that many women went on to adopt it as their own personal fragrance leading the house of Dior to the subsequent introduction of Diorella in 1972, composed by the same legendary nose, blending the green floral with hints of peach, honeysuckle, rose and cyclamen in addition to the herbal citrusy notes of the masculine counterpart, all anchored by a base of cool vetiver, patchouli and oakmoss, lending a mysterious, aloof and twilit air to women who went for it.

Ten years after its introduction to perfumery, in 1976, it was the turn of Jean Claude Ellena to coax hedione in a composition that exploited its fresh and lively character to great aplomb in the production of First by jewelry house Van Cleef & Arpels (the name derived from the fact that it was their first fragrant offering, but also the first scent to come out of a jeweler too ~subsequently many followed in its tracks with notable success). In it, Ellena used 10 times the concentration of hedione used in Eau Sauvage, married to natural jasmine as well as rose de mai (rosa centifollia, which is also a "crystalline" variety), narcissus, orris, ylang ylang and a hint of carnation with the flying trapeze of aldehydes on top and the plush of vetiver, amber and vanilla at the bottom which accounted for a luminous and luxurious floral.

Hedione also makes a memorable appearance in many other perfumes, such as the classic Chamade by Guerlain (introduced in 1969), Chanel no.19 (1970) and Must by Cartier (1981) and in many of the modern airy fragrances such as CKone, Blush by Marc Jacobs, the shared scent Paco by Paco Rabanne or ~surprisingly~ in the bombastic Angel by Thierry Mugler, in which it is used as a fresh top note along with helional! Perhaps if you want to feel it used in spades smell L'Eau d'Issey by Issey Miyake: the aquatic/ozonic notes cannot hide its radiance.
Its uses are legion, especially since it acts as a supreme smoothener of the rest of the ingredients. In Terre d'Hermes, perfumer Jean Claude Ellena uses lots of it to bring out the softer side of hesperidic bergamot and to fan out the woodier aspects.

High-cis Hedione is an isomer which gives a jasmine tea profile (not surprisingly, as the component naturally occurs in tea), more diffusive and less floral and thus useful in masculine blends, but it costs more than regular hedione and poses problems of stability in acidic environments. Some of the Bulgari "tea" scents, such as Bulgari Eau au Thé Rouge and Bulgari Eau au Thé Blanc are good reference points if you want to smell this in action.
Despite hedione's unlikeness to natural jasmine absolute and essential oil (which are much lusher, narcotic and indolic), perfumers have used it to supreme results in the history of fine fragrance of the last 40 years, occassionaly using it up to 35% concentrations, although it's more usual to be featured in ratios of 2-15%.

Related reading on Perfume Shrine: Perfumery Materials, The Jasmine Series

pic of jasmine via Gracemagazine. Bottle of First via zensoaps.com

Atelier Cologne Vanille Insensee: fragrance review & draw

“He wove through the crowd when suddenly his heart quickened. That scent. It was hers. He had worn it first until she stole it for herself. Now, there she was before him and the magic of years past came flooding back in a moment.”

These little snippets like stories out of a collection of romantic prose accompany the launch of Atelier Cologne niche scents and account for much of the brand's piquancy. Vanilla with its aprodisiac reputation seemed like the prime suspect into infusing a memorable, erotic perfume. And so Vanille Insensee arrived onto my desk. A vanilla...oh well, I thought at first!


Do you, like me, think vanilla fragrances are often juvenille and pedestrian, haunted by drugstore images of tooth-aching stuff that recalls more a bakery's back room than proper perfume? Or are you a vanilla aficionado always in the search out for the one perfect oriental which captures that elusive middle-ground between comforting and silky polish? A slew of niche brands are catering to your needs, it seems.

The comparison of Atelier Cologne's newest take on vanilla, Vanille Insensée, with others in the niche circuit, recalls both Diptyque Eau Duelle and Le Labo Vanille 44, but the effect is different enough to warrant its own exploration. For vanilla lovers (and they're legion) every little twist has the potential to make them want to sample and exhaust their repertoire. While Eau Duelle is more "clean musk" than promised woods and Vanille 44 is richer, like a sophisticated crème brûlée rather than dipping your nose into cake batter made with vanillin, Vanille Insensée brings on the freshness of vanilla to the fore. You heard that right: it's a crazy, fresh vanilla!

Atelier Cologne, founded last year by Sylvie Ganter (formerly of Hermès and FRESH fame) and Christophe Cervasel (founder of Selective Beauty, responsible for creating scents for John Galliano, Zac Posen, and Agent Provocateur to name but a few), they debuted "Petites" (30mls), soaps and candles last autumn and for spring 2011 they launched Vanille Insensée. Careful: That's not Incensée and it has nothing to do with incense! In French Vanille Insensée literally means vanilla out of its senses, vanilla in the most unexpected, profound, insane way!


Vanille Insensée was composed by perfumer Ralf Schwieger and in it the vanilla ~although front and central~ is given a diaphanous (yet lasting) treatment which seems lighter than what one would expect from the creator of waxy and intense Lipstick Rose (for F.Malle). Although advertised as "woody", I don't find Atelier's Vanille especially so. The citrusy touches on top (lime and cedrat, which is French for citron; but also spicy-orangey coriander) are classic allies in most orientals and here they lift the vanilla into the clouds, while clean notes of jasmine, white musk and mossy underpinnings (vetiver and oaky tannin smells) conspire to make the pod fluffy and "fresh" ~mind you, fresh and fluffy the way a meringue is just out of the oven, we're still on culinary grounds here. But away from choux à la crème land all the same...

If you want your vanilla intense, darkish and calorific, like Indult Tihota or Spirituelle Double Vanille (Guerlain) or rather smoky with layers of tobacco or cotton-candy & ice-cream cone, like, respectively, Havana Vanille and the discontoninued Vanilia by L'Artisan, then the Atelier Cologne version won't please. The same could be said if you're spoiled by the tropics treatment by the Comptoir Sud Pacifique line. If on the other hand you have always envisioned a vanilla to bring forth into spring and summer, with just the right amount of a sweet tooth that doesn't ruin the waistline, I think this one might do the trick.

A sample will be given to a lucky reader: What's your take on vanilla and vanilla fragrances? Say in the comments and I will pick a lucky winner. Draw is open till Friday midnight.

Notes for Vanille Insensée: lime, cedrat, coriander, jasmine, oak, vetiver, Madagascar vanilla, oakmoss and amber.

Atelier Cologne Vanille Insensée is vailable in 30 ($60) or 200 ml ($170) Cologne Absolue (15% concentration), carried by Bergdorf Goodman, Neiman Marcus and Steven Alan as well as the newly curated e-commerce website www.ateliercologne.com


In the interests of disclosure I was able to sample the fragrance assisted by the company who handles the brand.
Photo of vanilla sky via nettevivante

Perfumery Material: Coumarin, Tonka Bean & the Fougere accord

Open any perfume guide with fragrance "notes" or any online discussion or blog post on perfume description and you're bound to stumble on coumarin; one of the most common materials in many fine fragrances but also several body products, cosmetics and functional products. Its rich history goes back to the beginnings of modern perfumery in the late 19th century, bringing us right at the moment of the nascent concept of perfumery as a mix of organic chemistry and nature's exploitation. Coumarin as such is a synthesized material in most perfumes, but it's also found in abundance in natural products, such as tonka beans (Dipteryx odorata) where it is the principle aromatic constituent (1-3%). In fact the name derives from "cumaru", an Amazonian dialect name for the Tonka bean tree.

• Origin & function of coumarin

Chemically, coumarin is a benzopyrone (1-benzopyran-2-one) which, apart from tonka beans, also occurs naturally in vanilla grass (Anthoxanthum odoratum), sweet woodruff (Galium odoratum), sweet clover (Meliotus L.), sweet grass (Hierochloe odorata) and cassia cinnamon (Cinnamomum aromaticum) among other species. In short, it's rather sweet, as you might have surmissed by now, and evokes cut grasses. You'd be correct to assume both facts, but that's not all: Although coumarin in perfumery does add a certain sweet note of mown hay or freshly cut grass with vanilla overtones, it's really bitterish in flavour in high concentrations (its -now banned- inclusion in food would attest that). Therefore theorizing its plant origin one would assume it's produced by plants in order to defend themselves from predation. After all it's also present in cherries, strawberries, and apricots, prime targets for birds. You might have even seen it featured in your rodent pesticide: don't be alarmed (coumarin is included in miniscule quantities in foodstuff anyway), but now you know why!

• History of coumarin discovery & synthesis

Natural perfumers used and continue to use tonka bean absolute and tonka in powder form, as well as deer's tongue, a herb with brittle leaves to render a coumarin note. But the story of coumarin is largely one of organic chemistry. The component was isolated by A.Vogel in 1820, but the laboratory synthesis of coumarin first happened in 1868 from coal tar by W.H.Perkin (who gave his name to "the Perkin reaction" used to produce it). It took another year to produce it in an industrial scale at Haarmann & Reimer. The consequent memorable inclusion of synthesized coumarin in Jicky (Guerlain 1889) and earlier in Fougère Royale (Houbigant 1882) was the kickstart of a whole new fragrance family: the fougère, thanks to Paul Parquet's composition for Houbigant. Fougère Royale contained a staggering 10% coumarin of the finished formula! How one can dream a bit while reading Guy de Maupassant describing this fragrance as "prodigious evocation of forests, of lands, not via their flora but via their greenery"...

• The Fougere fragrance family

Fougère fragrances evoke the smell of ferns at least as we imagine them to be, as by themselves they don't have a particularly noticeable odour (Paul Parquet said that if they could, they'd smell of Fougere Royale). But the concept of a scent that is herbaceous, infused with aromatic lavender ~a popular material for both sexes at the end of the 19th century thanks to its propriety in the "clean" sense of the world~ and which leaves a malleable, soft, enveloping, yet discreet aura on the wearer was lacking: The era was still using the Victorian soliflores. Funnily enough, even those had their own categorisation; violets or roses for the respectable lady, jasmine and tuberose for the courtesan. Fougère scents were on the cusp between approved and revolutionary, creating a very desirable pull.
The other principle constituents in the accord are lavender and oakmoss: It was only natural; lavender by itself contains coumarin in its aromatic makeup. Thus the triad comprising the main accord of the rising fougère (i.e.lavender-oakmoss-coumarin, played together like a musical chord) made coumarin itself quite popular: many classic or influential masculine colognes owe their character to it, starting of course with Jicky and continuing with Azzaro pour Homme (1978), Fahrenheit by Dior (1988), Dolce & Gabanna pour homme (1994), and Gucci pour Homme (2003).
From there coumarin infiltrated its way into many modern fragrances belonging in other families. But it was its pliability and usefulness, like a trusty Swiss knife, which made it the perfumers' darling: Are there more contrasting fragrances than the icy aldehydic Rive Gauche (YSL 1970) and the intense floral Amarige (Givenchy 1991)? Perfumers tell me that coumarin ends up in some degree in 90% of all fragrances; and in concentrations exceeding 1% it accounts for over half of the fragrances in the market!!

• The odour profile of coumarin

Coumarin is a water-insoluble crystallized powder which has an odour that is pleasant, soft and warm, evoking cut grass or new mown hay, but it's more complex than that; it sometimes even veers into a smell of fresh paint! This is what gives Jicky its bracing almost "petrol" opening which alienates some people. Originally biosynthesized via hydroxylation, glycolisis and cinnamic acid cyclization, nowadays coumarin is produced via more sophisticated techniques.
Coumarin conjures warm notes of tobacco (useful in masculine formulae) and because it also has caramel overtones, alternatively it can be married to vanillic components (such as vanilla, benzoin or some of the other oriental balsams, such as Tolu balsam or Peru balsam, as well as ethylvanillin) in order to play down and sophisticate their foody aspects: see it in action in orientals such as the discontinued Venezia by Laura Biagotti, Lolita au Masculin(Lempicka) or Casmir by Chopard.
In dilution coumarin projects with soft hazelnut or almond facets underneath the hay, even licorice; smell Lolita Lempicka (1997). But in higher concentration it also has spicy fresh and herbaceous facets, no doubt reminiscent of its primary role in different grasses. In combination with vanillin and bergamot, we're veering into chypre territory: Elixir des Merveilles is a no man's land with its chypre tonalities and gourmand facets.
Its versatility and its ability to "fix" smell and make it last longer allows coumarin to enter amber or woody blends (witness Samsara or Vetiver by Guerlain) as well and even heighten the appeal of spicy materials: in fact it marries very well with cinnamon or clove. Pi by Givenchy is a sweet spicy woody with lots of tonka bean, or smell L de Lolita Lempicka by Maurice Roucel. Usually, indeed coumarin is mentioned in the form of tonka beans in the traditional lists of "notes"/pyramids for fragrances (see this Index for more ingredients contributing to which "note") but it can also hide underneath grassy notes, clover, lavender, or tobacco. Modern perfumers pair it with synthetic woody-amber notes such as Kephalis and Iso-E Super to surprising results. A wonderful material indeed!

• Fragrances featuring discernible amounts of coumarin

Addict (Dior)
A*men (Thierry Mugler)
Amarige (Gievnchy)
Angel ~all concentrations, esp. extrait de parfum(Thierry Mugler)
Angel Sunessence (T.Mugler)
Angel La Rose (T.Mugler)
Antidote (Victor & Rolf)
Azzaro pour Homme (Loris Azzaro)
Azzaro Elixir Bois Precieux (L.Azzaro)
Blue Jeans (Versace)
Bois des Iles (Chanel)
Brit (Burberry)
Chic for Men (Carolina Herrera)
Coco (Chanel)
Coco Mademoiselle (Chanel)
Contradiction (Calvin Klein)
Etoile de Rem (Reminiscence)
Fahrenheit (Dior)
Fieno (Santa Maria Novela)
Fougere Royal (Houbigant)
Florissa (Floris)
Gloria (Cacharel)
Jasmin Noir (Bulgari)
Jicky (Guerlain)
Joop! Homme (Joop)
Kouros (Yves Saint Laurent)
Lavande (Molinard)
L de Lolita Lempicka
Lolita Lempicka (L.Lempicka)
Le Male (Jean Paul Gaultier)
Musc (Molinard)
Navy (Lily Bermuda)
Pi (Givenchy)
Rive Gauche (YSL)
Samsara (Guerlain)
Tonka Imperiale (Guerlain)
Venezia (Laura Biagotti)
Versace pour Homme (Versace)

Related reading on Perfume Shrine: Perfumery Materials one by one

source of coumarin pic via The Health Nut Corner, ad for Houbigant via Punmiris and Jicky collage via Perfumesbighouse

Natalie Portman in Miss Dior Cherie 2011 Commercial

The sighs of Jane Birkin under Serge Gainsbourg's classic (and racy) "Je t'Aime...moi non plus" song are accompanying a new sexy siren of the 2000s: Natalie Portman, the newest face for Miss Dior Chérie, again directed by Sofia Coppola (as reported previously)and a viable Oscar contestant for her performance in Black Swan. It's funny to contemplate that the previous music choice for Sofia's commercial a few years ago was a tune by Brigitte Bardot, the very person who first sang the controversial orgasmic song by Gainsbourg; that version was revoked by her husband Gunter Sachs nevertheless. Serge then turned to Jane Birkin to record it to the outcry of the Vatican and the song became immortal in that version.

Nowadays it doesn't sound half as controversial as it did, but is the new commercial for Dior really reflecting the free sprit of the 60s and early 70s in an age that is so conservative despite the bom-bom swaying in hip hop videos and the public display of intimate personal details? "I am the wave, you the naked island"? "I go and I come in between your loins"? I think not...
Apart from a little suggestive play with a tie (posing as both a blindfold and a sort of leash) you'll have to squint your mental muscles into perceiving any more sexual innuendo in the Natalie Portman commercia!. The video is more romantic cliche than racy, although it's certainly more man-to-woman interactive than the previous "I fell fine trailblazing across Paris by myself" commercial by Coppola.
Talk about Natalie Portman stripping for the spot only resulted in her vaguely beginning to remove a few clothes with no more titillation, unless a bath tub scene where she's immersed up to her neck wearing sunglasses is considered risque. It looks like a shot from "Garden State"really, maybe a tip of the hat from the director. Sofia Coppola however really knows how to direct the whole into making us want to douse ourselves in overpriced Eau. Taking in mind I have an aversion to the overly sweet character of the original Miss Dior Chérie (but I do like L'Eau version), I find this is quite a feat! What do you think?

NB. The commercials are set to accompany the latest reformulation of the Eau de Parfum by head Dior perfumer F.Demachy.

Guy Laroche Fidji: fragrance review & history

Fidji by Guy Laroche, coming out in 1966, revolutioned the industry in more ways than one: First, it was at chasm with the previous French aesthetic perfumes coming out from French houses & designers. Here there was a fragrance which represented escapism, but that escapism was communicated in very American-shaped methods. Secondly, it showcased that apart from imaginative names (a tradition which knew some excellent examples in the past anyway), every perfume had to deliver a specific story, a story that would address a need and a desire of the audience to whom it was aimed at. Fidji succeeded beautiful but it also happened to be a beautiful perfume to begin with.

Composed by one of the unknown forces in the industry, nose Josephine Catapano, long before perfumers became rock-stars or began composing fragrances to evoke orgasmic effluvia, Fidji, a freshly green floral with tropical inclusions of ylang ylang and carnation, is a fragrance representative of its times and one which influenced many following it, such as Guerlain's Chamade, Cacharel Anais Anais, Chanel No.19, Givenchy III, Climat and even Charlie by Revlon. Fidji pushed to its extremities, on both ends of its skeleton, could be said to have inspired even Lauder for her bitter chypre Private Collection. After all, Catapano also worked for Lauder and IFF for years where she later became the mentor of Sophia Grojsman. Michael Edwards confirms my theory when he says:

[Fidji] “pioneered a new generation of fresh perfumes: Norell (1969), Charlie (1973), Gucci No 1 (1975) and a hundred other fragrances following its lead”.

Guy Laroche launched Fidji at a time when the youth market seemed like a particularly desirable budding segment to advertisers; what with the upheaval of the 1960s which brought out the power of young ideals and the romanticism of following your heart, and what with the desire of the young to map out their own territories, their own olfactory landscapes. These landscapes often revolved around the East or civilizations away from the Western anxieties...such as those of the South Pacific where the Fidji islands are located and the managers of the brand were taking their vacation when the idea formed. The Beatles were leaving for India and the hippies were gathering at Haight Asbury. Refound paradises were especially suggestive. The market demanded different approaches than the traditional "keeping up with the Joneses" social approach (a respectable perfume to assert one's spending power) or the heavy seduction games of old. Thus woman became "an island and Fidji was her perfume" as the memorable motto went. Women-isles through the years clutched the bottle closely to their smooth bosoms in the glossy images; women as famous as supermodel Linda Evangelista who posed for the ads in the early 1990s.

The olfactory inspiration for Fidji comes from another youthful (in its time) classic: L'Air du Temps by Nina Ricci. The salicylate heart with the clove-y tint was taken apart and enrobed in a new cloth, the rest modernised by Catapano accordingly and given a very fresh fuzzy start which is green rather than peachy, and a base with more patchouli and sandalwood which lasts well.

The opening impression of the Laroche scent is one of bitterish freshness with a cool (rather than warm) heart of flowers in which hyacinth pops its head, at odds with the modern expectations of a tropical evoking fragrance atavistically smelling of suntan oil and tiaré blossoms. Fidji isn't especially tropical despite the name and feels just as fitting in an al fresco lunch in the Hamptons in June, silk dresses in shades of paradise birds blowing softly in the breeze, as it does in an outdoor cafe in August-hot Barcelona with Verner Pantone S chairs laid out in orange and green. Its feminine sensuality is derived from the milky woodiness of sandalwood and the subtle musky trail it leaves on skin after the fresh floral notes and the mossy green dissipate; it behaves with delicate elegance and knows its place, even if it keeps its escapist fantasies close at heart.

Unfortunately, Fidji is among the creations which are best savoured in older formulations, as the modern Eau de Toilette, a rare sight at department stores or online, alongside its ancillary products, seems a bit thinned out, although still quite pleasant and many cuts above many more recent launches. Vintage Eau de Cologne concentration looks like a fine medium if you can't get yourself some of the old parfum. It's still available although rarer and rarer in some auction sites.

Notes for Guy Laroche Fidji:
citrus (lemon), galbanum, hyacinth, ylang ylang, carnation (via clove), spices, Bulgarian rose, jasmine, orris, vetiver, oakmoss, sandalwood, patchouli, balsam, musk, ambergris.