Sunday, March 8, 2009

Rotten eggs: Not what you Expected on the Last Word on Sexy!

If you have ever played with those filth-ampules at school that had the smell of vomit, excrement or rotten eggs, in the hopes of cutting classes due to the stink, little did you imagine that one of these days you'd find yourself looking at them with new appreciative eyes! The rotten eggs one especially, which you swore was the most abominable smell in the whole planet and which infested school halls for weeks almost. Well prepare to be given the shock of a lifetime and I am not making this up!

According to a study published in the scientific journal of the Proceedings of the National Academy of Sciences led by Professor Giuseppe Cirino of the University of Naples in Italy, studying eight men who had sex-change ops, the claims are: "We found that hydrogen sulphide is involved in human penile erection". As you might have uncredulously surmised by now hydrogen sulphide is a major odour constituent in nothing more aromatic than rotten eggs!
"The bizarre finding could help doctors to develop a more effective version of the sex drug Viagra. [...] A gas called hydrogen sulphide – also released when eggs rot and from the exhausts of cars with catalytic converters – is given out by men just before they have sex. Tiny amounts of it are released by nerve cells in a man's private part to prepare it for intercourse, a study found. The gas causes muscle cells in the region to relax, boosting blood flow, and leading to a better erection. Viagra, however, harnesses a different chemical – nitric oxide – to give users a boost. But one third of men have found the drug ineffective."
Hydogen sulphide has the chemical type H2S, is a colourless and flammable gas, and is produced in mammalian organisms from cysteine by the effect of various enzymes. It can also be found in volcanic gases, swamps and sewers via anaerobic digestion (that means in the abscence of oxygen) and is partially responsible for the foul odor of flatulence as well! Another proof that not everything we think applies in matters of science! Although very pungent at first, it quickly deadens the sense of smell, so potential victims may be unaware of its presence until it is too late...Let's not forget the Permian-Triassic extinction about 252 million years ago!(I'm so itching to crack a joke right now).

I guess the order of the day is: Ladies, you're stongly advised not to rely on this as a man-ensnaring device; and gents, please don't try it as a boost to your manhood!

I found the very interesting article through Minette of Scent Signals. You can read the whole article here.
Pic of partial Wilkinson Quattro Titanium ad via invertospot.com.

Winners of Sonoma Scent Studio lucky draw!

The winners for the Sonoma Scent Studio sampler-sets of Lieu de Rêves and Sienna Musk lucky draw hosted on Perfume Shrine are the following:

Dawn, Natalie, Audit Diva, Jenavira13, and Marin (antiM).
Please contact Laurie Erickson at Sonoma Scent Studio to claim your prizes, including a valid address so she can have these in the mail for you!

Thank you all for your enthusiastic participation and stay tuned for the next draw!

Friday, March 6, 2009

Iso E Super, its merits, its faults, Geza Schoen and Jean Claude Ellena

The chemistry of fragrances seems like an arcane side-path in the vast avenue of pretty smells. Those who venture there are either chemists, eternal students or people reading perfume boards. On those last ones, Iso E Super is nom du jour due to recent rumours of restricting its use to specific ratios in products (and they're many!) and due to its increasing popularity, some of it attached to the work of master perfumer Jean Claude Ellena who has experimented with its magic properties many a time in the past to glorious effect: Terre d'Hermès, Poivre Samarkande and Déclaration are utilizing lots of it, exploring minimalism: the play of scents note-for-note with no sentimentality attached. Even an entire composition, Molecule 01 by perfumer Geza Schöen of niche brand Escentric Molecules (his Escentric 01 also features it in high ratios along with pink pepper, lime peel, orris and incense) is composed of nothing else but it, diluted in solvent, because the perfumer loved it so! I am hereby reminding you that he is the perfumer who created HSIDEWS for artist Sissel Tolaas and he has collaborated with the London-based niche brand Ormonde Jayne. The theory behind Molecule 01 and IsoE Super was that it would create an appealing effect to those smelling it on the wearer without it being perceived as a "perfume"; the ultimate skin-scent, much like natural ambergris to which it mimics certain aspects would act. Another scent which officially contains it is Maitresse by Agent Provocateur, while the masculine fragrance Fahrenheit by Dior (1988) iincludes a 25% Iso E Super in the compound. In the legendary woody oriental Féminité du Bois by Shiseido, under the maestro Serge Lutens's direction, the material serves as an harmoniser between the plummy effect of the fruits with the violet ionones and the cedarwood bottom notes. Iso E Super is used in so many fragrances today that it would be hard to compile an actual list that would not bore everyone silly! But what the hell is Iso E Super?, you might ask. Let's take matters at the top.

Iso E Super® is the trademark name of aromachemical 7-acetyl, 1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl naphthalene and I guess it's pretty obvious why it's called that instead of its long organic chemistry name. According to International Fragrances and Flavors Iso E Super is
"Smooth, woody, amber with unique aspects giving a ''velvet'' like sensation. Used to impart fullness and subtle strength to fragrances. Superb floralizer found in the majority of newer fine fragrances and also useful in soaps. Richer in the desirable gamma isomer than isocyclemone e".
Arborone is the odor active enantiomer of Iso E Super, with its clean woody and pleasing aroma.[1] The uses of Iso-E Super are legion: from bleach and deo sticks to soaps, shampoos, laundry detergents and fine fragrance. Given that its colour is almost transparent to very light yellow it poses no problems in being incorporated in formulae and is also used in the pharmaceutical industry.
Despite the IFF being the company to trademark it, Chinese companies such as Zhejiang Winsun Imp. & Exp. Co., Ltd. do provide it at a concentration of 90% for various uses. Home-made mixes would suggest one part Iso-E Super to 9 parts base, such as dipropylene glycol/perfumer's alcohol (therefore a 10% concentration). Although neat use on skin isn't recommended, minor "accidents" of spillage have not produced anything sinister. Taking in mind that it is quite inexpensive, it is perhaps of interest for apprentices and amateurs alike to experiment themselves at high dilution.

Smelling it in itself one is surprised by how almost non-existent a smell Iso-E Super has; not something one would describe as a smell in so many words, it's unapologetically synthetic and perhaps vaguely cedar-like, slightly sweet. It seems to vanish very quickly and resurface on skin in intervals from time to time very discreetly: The heat of the skin is intergral to its volatilising properly and it seems that any test on paper would not give an accurate perception of its true nature. It is however quite recognisable once you get to sample it and you will have fun detecting it in many major fragrances on the market todat. This subtle "skin-scent" effect is what in perfume-lingo is used to evoke that a fragrance stays close to the skin, not projecting in a wide radius; but also that it has some skin compatibility effect that makes it smell not like a usual perfume. Therefore IsoE Super soon gained the reputation of it acting like a pheromone, that invisible aroma that is supposed to attract same species potential sexual partners and ensures recognition of compatibility between mates. Plainly explained, pheromones act to the vomero nasal organ ensuring that pigs mate with pigs and not rhinoceruses for instance! Much as the matter is exciting and intriguing hower, the scientific community has not been able to conclusively establish validity in the theory of pheromones working in humans so far, although popular mythology is rampant with examples of products aimed to achieve this magical attraction (such as Androstenol, Androstadienone, and Androsterone). In an interview given by perfumer Geza Schöen on the creation of Molecule 01, he intimated:
"When I was introduced to ISO E Super in 1990 I gave it to a friend of mine to wear. We went out to this bar in our hometown and it took only a few minutes until this woman steered straight into our direction to inquire about who smelled so lovely! Since then I knew that this stuff is special indeed. I suggested it to the guy who was in charge of Diesel back then and he said that he felt that this is a bit too much - even for them!" [2]
He's quick to elaborate however that it does not act as a pheromone (that's a misconception if scientifically examined) but that simply it's "not possible not to like it", as no one has ever commented he/she doesn't like its particular smell per se.

Perhaps the most vexing matter to perfume enthusiasts however has been how Iso E Super is one of the 14 chemicals that have been recommended for study by the National Toxicology Program (NTP) with impending restrictions on its use. Ever since as early as 2000 the matter has been in discussion. In a letter by Betty Bridges, RN Fragranced Products Information Network (http://www.fpinva.org/) addressed to Dr. Scott A. Masten, Ph.D. from the Office of Chemical Nomination and Selection, Environmental Toxicology Program of the National Institute of Environmental Health Sciences in 2002 we read the following:
"International Flavors and Fragrance's suggested use levels of Iso E Super is up to 10% of the fragrance formula and is recommended for use in a variety of products (IFF, 2002). Isocyclemone E's (a material with a different ratio of isomers, same CAS# 54464-57-2) suggested use level is up to 30% and is recommended in a variety of applications.(IFF, 2002) [...] Considering Iso E Super's similar structure to AETT and AHTN, two polycyclic musk compounds with known concerns, it is likely that Iso E Super and other chemically similar materials would also bioaccumulate in human tissue, persist in the environment, and have health concerns. There are concerns related to AHTN causing liver toxicity and discoloration. Galaxolide, another polycyclic musk has similarconcerns, but to a lessor degree (SCCNFP, 2000) Chromogenic properties have been associated with neurotoxicity (Sabri, 2002)"
Before publication of the 43rd amendment issued by IFRA it had been rumoured that Iso E Super should be a restricted raw material. This doesn't mean that it is not to be used any more as novices often assume erronesouly. It simply means that it should be incorporated in a formula below a certain level for it to be commerialised (and of course one could do whatever they pleased if they made a do-it-yourself formula at their own labs/homes!). On the other hand another aroma material, Boisvelone (C16H26O) closely related to Iso E Super (but reportedly a little more elegant; I haven't tried it myself while one source[3] reports it as the exact same thing) has disappeared from commercial use. According to one perfumer currently teaching [4] however, a feminine "alcoholic" product (that means an eau de toilette, eau de parfum or extrait de parfum ~generally any product with an alcohol base) there is a limit of approximately 20% of Iso E Super in the final product. Although it might seem like a lot, if you are composing an Eau de Parfum, which means a 15-20% dilution, you're well within limits still even if the entire fragrance consists of Iso E Super. Luckily for all of us, the latest amendement of IFRA can be downloaded here and it seems to make us sigh a sigh of relief for now: Iso E Super is not yet restricted. ** [Please see addition on the bottom for current info on IFRA approved ratio]

Hot on the heels of the sinister rumours was the prevalent concern of perfume lovers whether the fragrances that feature it (with Jean Claude Ellena's most prominently) would suffer from it. It was only the other day that the matter was brought again to the table on this very venue, while discussing Déclaration by Cartier, one of the most influential of Ellena's fragrances. Since the objective of Perfume Shrine is to be very clear in what is only a hypothesis on our part and what is a matter of fact, we took things in our hands to further investigate and the resulting message is even more assuaging, discouraging you from frantic stocking-up of fragrances which you would fear would be unrecognisably altered. The fragrances by Jean Claude Ellena will not be altered or influenced by any -as yet only suggested for the future- restrictions of Iso-E Super ratio as they are already well below the ratio proposed for the restrictions. The information is official and comes from mr. Jean Claude Ellena himself. I hope this article proves useful to you!

Here is a table of Top Ten Fragrances with Regard to Their Content in Iso E Super
No., Fragrance Name (Company, launch year), Iso E Super
[NB. the percentage is in regards to compound, not diluted ready to use product]

1 Molecule 01 (escentric molecules, 2005) 100%
2 Perles de Lalique (Lalique, 2007) 80%
3 Poivre Samarcande (Herme`s, 2004) 71%
4 Escentric 01 (escentric molecules, 2005) 65%
5 Terre d'Hermes (Hermes, 2006) 55%
6 Incense Kyoto (comme des garcons, 2002) 55%
7 Incense Jaisalmer (comme des garcons, 2002) 51%
8 Fierce for Men (Abercrombie & Fitch, 2002) 48%
9 Kenzo Air (Kenzo, 2003) 48%
10 Encre noire (Lalique, 2006) 45%

Ref for table: Schon G. 2008. 'Escentric' molecules. Chemistry & Biodiversity. 5 (6) :1154-8. In June 2008. Verlag Helvetica Chimica Acta AG,Zurich


EDIT TO ADD/AMEND 2011: At the time of writing this was the correct info. As of 2011 however the IFRA industry regulating body has set a maximum dilution limit of 21.4% in the compound. Jean Claude Ellena's scents and the majority of scents using it are relatively safe, as a mere 1% in the formula in enough to provide the qualities it's famed for, but it is the updated info for anyone caring to use it in their own formulae.


References:
[1]Helvetica Chimica Acta, Volume 82, Issue 7, Date: July 7, 1999, Pages: 1016-1024
[2]I heart Berlin.de
[3]Nextbio.com
[4]J'aime le parfum!

Pics from Iheartberlin.de and Hermes.

Wednesday, March 4, 2009

Narciso Rodriguez Essence: fragrance review

Narciso For Her by young, hip and understated designer Narciso Rodriguez had me at hello all those years ago with its delicious musky trail that is too sexy for words, yet polished enough to pass off as classy; ever since the brand has me curious as to what they come up with next. Proving to be a mega-trendsetter ever since its launch, Narciso for Her catapulted the market into a gene-pool sharing the same musks and "clean" synthesized patchouli bases shaped into the beautiful but traitorous dress of the "modern chypré"; in moments of truth and Sundays' waking up too late after a night partying next to delicious-looking strangers those scents shed that pretentious dress for the comfortable and more accurate flannel PJs of "woody florals with musks" and that's perfectly all right by me. But I digress... Luckily for all of us, the tremendous success of Narciso For Her didn't wind the Rodriguez brand into mechanically and pacingly launching myriads of "flankers"; with the exception of slight differences between the original range itself (eau de toilette vs eau de parfum vs parful roll-on vs Musk For Her oil) and the masculine counterpart issued one year ago, they have restrained themselves into an elegant rhythm which I respect.

Essence, Rodriguez's newest feminine fragrance, didn't grab me as much as Narciso For Her initially did, but that doesn't mean it is a bad fragrance; on the contrary it has a strangely insidious, undercurrent appeal of being made by very skilled hands who were given a not-too-precise-brief and although I am snobishly trying to write it off as repetitive and trite, I can't really. In Essence Rodriguez collaborated again with Beauté Prestige International, the Paris-based fragrance division of the Shiseido Cosmetics Corporation, aiming to capture a "sensual and luminous fragrance with a modern heart of musc enhanced by radiant notes of rose petals, powder notes of iris and hints of amber resulting in a floral, powdery musc fragrance". It doesn't sound terribly exciting, it utilizes the same well-known notes that Narciso Rodriguez obviously loves and I bet that the Spanish-born perfumer Alberto Morillas of Firmenich ~at once a classicist and a modernist and amazingly prolific in his almost 40-years-long career~ could have provided the formula with both hands tied behind his back and blindfolded at the drop of a hat! A recipient of numerous awards, among them the coveted Prix Francois Coty in 2003, Alberto Morillas is responsible for such bestsellers as Armani's Sensi and Aqua di Gio, Bulgari Blu, Omnia and Thé Blanc, Carolina Herrera Chic and 212, Cartier's Le Baiser du Dragon , M7 for YSL, Marc Jacobs Daisy and of course another huge influence on the market: Flower by Kenzo. The man knows how to attract the audience's loyalty, therefore enough said.

The overall effect of Narciso Rodriguez Essence is a clean unctuous almost soapy/aldehydic scent with classical mementos of White Linen minus some of the sharpness and Chanel No.5 minus the sweet florals or the skanky sexiness of lacy panties underneath prim suits, yet with an eerily reminiscent warm-skin-feel that the original Narciso for Her possessed as well. The clean musks featured, with their lathery bubbliness, have their lineage in Morillas's 212 and Daisy, while the powdery segment takes a page off Flower. Little development happens from the initial dryer-sheet sharply aliphatic and abstractly floral opening to the polite muskiness skin-like effect of probably Ambroxan*, (wishful-thinking) Muscenone** and Habanolide**. For what is worth the current modern white musk accord was first created by Alberto Morillas himself in Emporio Armani White for Her (combining Habanolide to Helvetolide**) and he used Muscenone in both Flower and Vanille 44 for niche brand Le Labo. The whole pared-down approach reminds me of the Escentric Molecules line. Although the powdery hazy effect is often attributed to iris, I do not detect any of its melancholic earthiness in the composition, same as with Infusion d'Iris by Prada which utilized a similar approach to the upscale-shampoo-latheriness vibe which seems to be all the rage now (judging by even such offerings as Chanel's Beige from Les Exclusifs). Luckily for the anosmiacs to Narciso For Her it seems to be rather different, enough to maybe give a jolt to their hypothalamus and be discernable to them.

Rodriguez wanted Essence to represent duality: "the intense and the ethereal, the simple and the complex" with an emphasis on "sun's purity" which reminds me of the "solar musks" accord of his first feminine perfume. I guess it's shorthand for "clean and warm" which Essence most certainly is. Lovers of that unperfume-y aspect as well as adventurers of all things delicately musky should flock to at least try it, the rest might find it non remarkable or even unpleasant in its screechy soapy tonalities which overstay their welcome impressively. It's pleasant enough for people into that genre, quite unisex and rather fun (for the price asked) to wear when that Sunday in flannels comes around once in a while, although not as enjoyably fulfilling as the original Narciso for Her is.

The bottle glows from within its mirrored core, round in its glass curvaceousness, created by noted industrial designer Ross Lovegrove (recipient of the prize Royal Designer for Industry in 2004 and art-exhibitor at MOMA and Guggenheim Museum in New York, the Centre Pompidou in Paris as well as the Design Museum in London). The eye-catching design is almost a futuristic, rounded interpretation of the original solid and austere Narciso For Her flacon.
The advertising campaign shot by the lens of Inez van Lamsweerde and Vinoodh Matadin
features supermodel Catherine MacNeil to whom Narciso "was drawn to instinctively".

Notes for Narciso Rodriguez Essence:
iris, rose, benzoin, modern musks


Narciso Rodriguez Essence is available in Eau de Parfum 50ml/1.7oz and 100ml/3.4oz exclusively at Saks Fifth Avenue from March and globally in April.
Ancilary products include a body lotion, a bath and shower cream and a deodorant spray.

Ad pic via fibre2fashion.com , soap courtesy of sassylicious.com.au

*Abroxan is a synthetic aromachemical mimicking the ambergris sensuous note.
**Muscenone, Habanolide, Helvetolide are gtrademark names for different varieties of synthetic musks.

STR8 to the movies

Of all the very successful commercials of the Sarantis Group for their fragrances (C-THRU, B.U., Xpose etc) the ones which made more of an impression to me due to their very cinematic and sensuous nature are the ones for the masculine fragrance STR8 (ie. straight), titillating without being vulgar and with small details that make them a little "story" in themselves.

The constants are cars, American "heavy" cars in particular with their big skeleton of steel, expanses of skin mapped like roads, darkness and light, liquid drops oozing like pearls and teeth (mechanical and otherwise) gnawing on soft parts...

The first one set the tone under the haunting notes of Motorpsycho's Stalemate with its rhytmic staccato echoing the editing "cuts".



The one to follow had a gothic-vampiric feel seen through the masterful direction of Eric Barbier and the jazzy ambience of The room by Sillyboy.



The newest one makes the very American Kerouak's On the Road take a whole new dimension with the long-winded J.Butterfly from the longplay "From One Human Being To Another" by Mourah.



All clips originally uploaded on Youtube.

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