Definition: Resinous & Balsamic Fragrances

One of the most elusive terms in fragrance terminology appears to be -according to readers' comments- "resinous" and "balsamic", as relating to perfumes. The raw materials falling under the umbrella of resins and balsams are among the most ancient components of perfumes, often the basis of the Oriental family of scents and lending their soothing opulence and depth to other families, such as the Chypres. They make their appearence known in any category though: florals, fougères, hesperidics also benefit from a touch here and there.

The distinction between resin and balsam is one of form, on a fundamental level: Simply put and generalising, resinous materials come in the form of solidified, gum-like "tears" seeping from the elixir vitae circulating into the bark of big trees, such as the Boswellia Carteri (which produces frankincense). Balsams on the other hand are trickly materials, not necessarily tree secretions, often coming as they do from flower pods or bushy twigs (such as vanilla orchids or the Mediterranean rockrose). But there are exceptions to every rule: Opopanax, though resinous smelling itself, actually comes from a herb, opopanax chironium.
So the real focus when referencing balsamic and resinous terminology is how the materials actually smell and how they're different or common in scent, rather than what their origin is. 
Therefore, for ease, resinous & balsamic materials are classified into 3 distinct olfactory profiles according to their aromatic properties first and foremost.

Soft balsamic smelling ingredients include:

• vanilla (from the vanilla orchid, the rich pod having a more complex rum-like note than the popular synthetic ethyl vanillin)

• benzoin gum (from Styrax Tonkiniensis with a sweetish, caramel and vanillic facet; benzoin Siam or benzoin Sumatra are used in perfumery)

• Peru balsam (coming from the Myroxylon, ~literally "fragrant wood" in Greek~ or Quina/Balsamo, a different species of which also produces Tolu balsam)

• Tolu balsam (close to Peru balsam, but a little sweeter and fresher)

• cistus labdanum (leathery, ambery, deep, coming from the rockrose bush and traditionally harvested from the hairs of goats who had grazed on the rockrose).

These materials have a gentle tone, while at the same time they're softly enveloping and have a pronounced character. They fix flowers into lasting longer and thanks to their properties when used in large quantities produce the semi-Orientals or the florientals (in conjunction with rich floral essences). 
A great example of a fragrance featuring copious amounts of Tolu balsam is Tolu perfume by Ormonde Jayne. The opulence of the balsamic note mollifies the rest of the composition, giving the golden sheen of a multi-faceted citrine. Tolu also makes floral notes more candied: in Fracas by Piguet it acts on the tuberose, on Gold by Donna Karan it enhances the ambery lily.
Compare and contrast with the balsamic base of Guerlain's Vol de Nuit which features a generous helping of Peru balsam; the oriental accord gives it its opulence under the green top note. In Ambre Sultan by Lutens, Peru balsam pairs with its traditional counterpart, an oriental amber accord. Elixir des Merveilles is another one which features balsam of Peru for its sweetly grounding qualities.

For labdanum, grab Donna Karan Labdanum, L'Air du desert Marocain by Andy Tauer, La Labo Labdanum 18 or Madame X by Ava Luxe: they're full of it.
The purest incarnation of benzoin in non gum form is Papier d'Armenie, the traditional scented little papers in a cute notebook, which burnt produce a clearing, anti-microbial atmosphere to one's home. Short of that, if you don't travel to Europe often, you can get a sample of Bois d'Armenie by Guerlain, or Prada Candy. Benzoin is very versatile spanning the fragrance families from citrus to woods and florals and its heft is therefore used frequently as it complements the other notes beautifully. Chanel's Coromandel fuses the vanilla-cinnamon notes of benzoin with a white chocolate note to render a delicious and sophisticated gourmand fragrance. Both benzoin and Tolu balsam make up the surprisingly monastic backdrop of Bal a Versailles by Jean Desprez, allied to the austerity of cedar.

If you are seeking a lush balsamic composition with multi-nuanced orientalia, seek no further than Mecca Balsam by La via del Profumo; it features labdanum, real oud and franckincense as well, so it's a composite that allows one to see how categories can be combined.

Vanillic fragrances are of course widely understood by everyone, so another article of a different scope, focusing on their merits and faults, is in order.

Resinous balsamic smelling ingredients include:

• opoponax/opopanax (also called "sweet myrrh" ~though no relation~ from the Opopanax chironium herb, scented between lavender & amber)

• frankincense/olibanum (the lemony-top, smoky smelling "tears" of the Boswellia carteri tree, called lubbān in Arabic)

• myrrh gum (a waxy oleoresin with a bitterish profile from the Commiphora myrrha)

• birch tar (from "cooked" birch wood, tar-smelling)

• elemi (a peppery, lemony, pine-like yellow oil coming from the steam-distilled or treated with volatile solvents resin of the Canarium Lizonicum)

• styrax (resin from the Liquidambar Orientalis tree, with a scent reminiscent of glue and cinnamon)

Valued since antiquity, resins have been widely used in incense and perfumery. Highly fragrant and antiseptic resins and resin-containing perfumes have been used by many cultures as medicines for a large variety of ailments. It's no coincidence that the three Magi gave baby Jesus the gifts of Frankincense, Myrrh and Gold. Traditionally used to make incense (King Solomon regarded opoponax as the noblest incense gum), even nowadays in the Middle East and the Mediterranean basin frankincense and myrrh "tears" are the incense par excellence still. These materials are deeper, with a lingering trail which adds originality and projection to a composition. Since they themselves typically come from the bark of trees in the form of crystalised resin "tears", they pair very well with woody scents.

If you want to get a taste of how some of the more "esoteric" of these smell, , say opoponax grab yourself the Diptyque Opopanax scent in either room spray or candle, as well as their Myrrh candle. They provide the scent in isolation. The iconic Shalimar as well as the masculine counterpart Habit Rouge owe their "flou" hazy effect in opoponax allied to orange blossom. For myrrh, Myrrhe Ardente in Les Orientalistes line by Annick Goutal and La Myrrhe by Serge Lutens provide two nuanced and quite different "readings" of the myrrh gum in complex compositions.
Athonite frankincense in the black variety is pure frankincense/olibanum gum (it's pliable when you rub it, like chewing gum), rising in clean, citrusy-smoky ringlets on the air; I burn it on small coal tablets regularly. There are many frankincense fragrances in the niche market, the truer perhaps being Avignon by Comme des Garcons, but the whole Incense Series is to be explored for the truly interested perfume lover.
Tauer's Incense Extrême is a good starting place for frankincense variants, based as it is on the Boswellia serrata (Indian incense) at a 25% concentration.

Birch tar is easily detected in compositions of the Cuir de Russie type (from Chanel Cuir de Russie to Piver's and Guerlain Cuir de Russie). This is also a material that can be classified in the sub-group of phenolic smells. It is pungent and dark.
Elemi is often used in masculine blends to give at the same time cooling piquancy and warmth thanks to its peppery top note: try Gucci by Gucci, notice the top note of L'Instant pour Homme (Guerlain) and the unique Eau de Naphe by Comptoir Sud Pacifique. For styrax, remember that the resin has a leathery facet with incense tonalities (and has been an important supporting player in "Cuir de Russie" compositions, such as Chanel's). Notice it in the drydown of Carven's Ma Griffe, in Poivre 23 by Le Labo and in No.11 Cuir Styrax by Prada. Lutens uses it beautifully in several of his scents, notably in the base note of Tubereuse Criminelle and Cuir Mauresque.

Nota bene that even though fir, pine and copal essences come from coniferous trees themselves,  I am not including them in the resinous and balsamic classification as they're really terpenic-smelling (a perfume definition to be elaborated on in a subsequent article).

There is also a sub-set of powdery balsamic smelling ingredients which do not come in resin or balsam form, therefore they are not classified into this category via origin at all, but rather via their scent profile alone. This includes: orris root (the Iris Pallida rhizome and also the synthetic irones-rich reproductions), several musks of synthetic origin, and carrot seed oil (which can give an orris scent in itself).
Amber mixes (refer to what amber is and its difference from ambergris on this link) can also be powdery balsamic smelling: the inclusion of benzoin (which gives a sweetish, baby talc note) and vanilla in the mix of ingredients in amber is the culprit. In French terminology/classification of orientalised perfumes they're refered to as "parfums ambrés" (even when not entirely focused on amber). For instance Obsession, the original Magie Noire (not the reformulated which is greener, more chypre) or Moschino by Moschino (again the original from 1987) are examples of perfumes "ambrés". It is important NOT to confuse between a balsamic/ambery powdery ambience (which is typically sweeter) and one which is powdery/dry (such as in Aromatics Elixir, Ma Griffe, Flower by Kenzo, DK Cashmere Mist): the two terms though very close are not interchangeable.

In concluding, the necessity of establishing a common language for scent among people who talk about the same perfumes increasingly arises. Even though we commonly use subjective terms to denote our feelings, the proper terminology, in accordance to how perfumers talk among themselves, aids a thorough understanding  and enhances our communicating our impressions on an immediately graspable context. It is this need which we try to address with our articles on Perfume Vocabulary and Definition on PerfumeShrine. If you haven't caught up with our relevant articles, here's what you might have missed:

• Definition: Indolic vs. Non Indolic
• Definition: Lactonic, Creamy, Milky, Butyric
• Definition: Powdery & Dry in Fragrances
• Definition: Soapy in Fragrances
• Definition: Phenolic, Terpenic, Camphoraceous scents
• Definition: Which Material Produces Which Note/Effect?

Photo of resin drops, some rights reserved by flod/flickr, censer pic via St.Dunstan's Priory

Labdanum: an important material (in chypre fragrances & not only)

It is well known to our readers by now that chypre perfumes are dependent on a strict formula that juxtaposes bergamot and oakmoss, interlaying labdanum and other earthy elements such as vetiver or patchouli.
Perfume Shrine has already focused on oakmoss extensively (click for relevant article), so the other important material that needed tackling was labdanum. And so here we are today, trying to examine some of its facets.

First of all, what is it? It comes as a sticky dark brown resin exudate from two sources: from the shrubs Cistus ladaniferus (western Mediterranean) and Cistus creticus (eastern Mediterranean), both species of rockrose. Rockrose forms the Cistaceae (or rock-rose family), a rather small family of plants reknowned for their beautiful shrubs, covered by flowers at the time of blossom. It consists of about 170-200 species in eight genera and those are distributed primarily in the temperate areas of Europe and the Mediterranean basin, although they can be found in North and South America too in some instances. The flowers themselves have a faint odour and are not used in perfumery.

Labdanum is a natural oleoresin but it differs slightly from other oleoresins in that it contains more waxes and less volatile oil than most of the other natural oleoresins.

There is an ancient background to labdanum, as its etymology reveals: lôt in Hebrew (coming from a semetic root) which means resinous herb, ladunu in assyrian, lâdhan in Arabic, ledanon in Greek and ladanum/labdanum in Latin. Egyptians used it in their Kyphi mixtures whereas the Hebrews burned it in their temples as incense, so it had a ceremonial character.
It is even referenced in The Bible (as Balm of Gilead): The Ishmaelite caravan coming from Gilead to which Joseph was sold, was transporting labdanum (Genesis 37, 25). Subsequently, Jacob ordered his sons to offer labdanum, along with other local products, to their brother, now an Egyptian dignitary:

"And their father Israel said unto them, If it must be so now, do this; take of the best fruits in the land in your vessels, and carry down the man a present, a little balm, and a little honey, spices, and myrrh, nuts and almonds."

(Genesis 43, 11) {found through Bible fragrances}.

It is believed that the above refers to the resin from the Pink Rockrose as "myrrh", although the two are not interchangeable. Myrrh per se is mentioned in the Bible (Psalm 45:8; Song of Solomon 4:14) and is believed to have been a mixture of natural myrrh (extracted from a tree in Africa and Arabia, like franckincense used to be got as well) and the oleoresin labdanum.

The Japanese use labdanum today in their Neriko mixtures, used during tea ceremony. The tradition is alive!

The use of ladbanum in medicine is well documented. Its high content in polyphenols makes it an excellent food supplement protecting the immune system.
In ancient times it was used for its properties of protection against bacteria and fungi.

It is suggested that the Pharaohs used fake beards made of goat hair (from animals that had grazed upon the resiny bushes) for that reason, but also to surround themselves with an aura of distinction.
Greek physician Hippocrates prescribed "myrrh" (the mixture of natural myrrh and labdanum, as above) for sores and the Romans used it to treat worm infestations, the common cold, coughs, and some infections. Up to 3000 tons of frankincense and myrrh were transported each year during the height of Nabataean trade!
According to Cocker, J. D.; Halsall, T. G.; Bowers, A. (1956). "The chemistry of gum labdanum. I. Some acidic constituents" (Journal of the Chemical Society: 4259-62) and II. The structure of labdanolic acid" (Journal of the Chemical Society: 4262-71):

Labdane is a natural bicyclic diterpene that forms the structural core for a wide variety of natural products collectively known as labdanes or labdane diterpenes. The labdanes were so named because the first members of the class were originally obtained from labdanum, a resin derived from rockrose plants."

while

A variety of biological activities have been determined for labdane diterpenes including antibacterial, antifungal, antiprotozoal, and anti-inflammatory activities.

(Studies in Natural Product Chemistry : Bioactive Natural Products, Part F, Atta-Ur-Rahman)

Theophrastus and Pliny mention labdanum as does Herodotus in his Historia, in the book "Thalia" (one of a total of 9,named after the Muses):

"Ledanum, which the Arabs* call ladanum, is procured in a yet stranger fashion. Found in a most inodorous place, it is the sweetest-scented of all substances. It is gathered from the beards of he-goats, where it is found sticking like gum, having come from the bushes on which they browse. It is used in many sorts of unguents, and is what the Arabs burn chiefly as incense.
Concerning the spices of Arabia let no more be said. The whole country is scented with them, and exhales an odour marvellously sweet."

{*please note that the Arabs referenced by Herodotus are ancient tribes inhabiting the region called Arabia and not today's islamic populace}.

But then why the confusion with opiates? The answer goes back to the Middle Ages and Paracelsus. A famous medical preparation of his own -which included gold, crushed pearls and other ingrendients (Opera, 1658, i. 492/2), but with opium as its chief component. Therefore the term is now used for the alcoholic tincture of opium (q.v.). The name was either invented by Paracelsus from Latin laudare (=to praise), or was a corrupted form of "ladanum" (from Persian ladan), a resinous juice or gum obtained from various kinds of the Cistus shrub, formerly used medicinally in external applications and as a stomach tonic." (Source 1911encyclopedia.org)


Labdanum's odour profile is highly complex. It is balsamlike, with woody, earthy, smoky, and even marshy undertones. Some even desrcibe it as ambergris-like, or leathery and honeylike with hints of plum or oakmoss after a rain. Usually it is referred to as ambery, but it is mostly used to render leather or ambergris notes, the latter especially after its ban on using the real animal-derived material, as there were concerns about the ethical production of it from sperm whales from which it originates (Ambergris is therefore very rare and costly if ethically harvested and is mostly synthesized in the lab. Please read this amber article for more info).

Its complexity is one of the reasons it has fascinated people since antiquity and it has been reported to affect the subconsious in profound ways. Its aromatheurapeutic value is that it is grounding, warming and sensual.

The method of extracting it is unusual and highly entertaing at that. Herodotus and Pliny report that labdanum was collected by combing the beards of goats, which were impregnated with the substance. The goats graze from the branches and the sticky resin gets stuck on their beards. Upon their return, their owners comb the resin our of their beards and extract the resin.

Also a rakelike instrument with long strips of leather attached to it, which they drag across the bushes to collect the resin, is used, called ladanesterion.
To this day labdanum is still gathered in Crete by driving goats into the thick forests overgrown with labdanum bushes. It is difficult work as it is best done in hot weather, under bright sunlight in the summer months. Sises is a Cretan village near Rethymnon, where such work is done to this day (coincidentally also the area from which El Greco/Dominikos Theotokopoulos comes).
You can read amazing detail on this matter on this site by Dimitris Niktaris: Labdanum Gr.

Today modern production is mainly concetrated in Spain and is done through easier means. However there is something to be said about the small, manual labour of cretan production that is of top quality.
The modern method involves boiling the leaves and twigs of this plant in water and the gum being skimmed off the surface and mixed with other resinous matter, which sinks to the bottom of the boiling water, as the resinoid is unsoluble in water. The extraction of the crude or cleaned labdanum gets done with a hydrocarbon solvent, whereas petroleum ether is being used increasingly because it yields a light amber resinoid which contains the most wanted odour principles in high concentration: cinnamon base - (isoeugenol) and labdanum resinoid. An absolute is obtained by solvent extraction whereas an essential oil is produced by steam distillation.

In perfumery it is used in many alloys, chypres notwithstanding and mixes well with hundreds of ingredients, interestingly one of which is lavender, another mediterranean herb.
Labdanum gum may contain up to 20% water, but this should be squeezed off or cautiously dried off. When in its fresh state, it is plastic but not pourable. It hardens on ageing, even to the point of becoming brittle. However if it is so at room temperature, it should be rejected as a starting material for the processing of labdanum derivatives.
Its shelf life is about 36 months and can be used in 10.0000 % in the fragrance concentrate.

One of the fragrances that focus on labdanum is Le Labo's Labdanum 18. Tagged as an enigma, to be used by both sexes, it focuses on the mysterious ambience that labdanum creates, fusing animalic and warm notes that meld on the skin.
Other fragrances that are rich with the note (but no guarantees on it always being naturally derived) are:
Donna Karan Essence Collection Labdanum ,Monia di Orio Lux, Dia for men by Amouage, L'eau Trois by Diptyque, Rien by Etat Libre d'Orange, Andy Tauer L'air du desert marocain ~Click for review~ (and reportedly it will feature in his Incense Duo as well), Patou pour Homme, Tabac Sport by Mäurer & Wirtz, Boucheron Pour Homme, Capucci Pour Homme, ST Dypont Signature pour homme, Eau Sauvage Extrême by Christian Dior, Whole Notes a floriental from Canadian perfumer Lyn Ayre of Coeur d’Esprit Natural Perfume, Prada, Prada Tendre and Prada Amber pour Homme, Mathew Williamson Incense, Ho Hang by Balenciaga, Jacques Bogart One man show, Ayala Moriel natural perfumes Ayalitta, Autumn and Democracy and Anya's Garden natural perfume Pan ~click for review~ that features real billy goat hair tincture.

Pics from bojensen.net, ladanisterion pic originally uploaded by labdanum.gr