Thursday, December 24, 2009
Merry Christmas to You!
I am on a short trip but will be returning soon. I am leaving you with Gaudete , an early Latin Christmas madrigal, here performed by the Oxford Camerata.
Wednesday, December 23, 2009
Andy Tauer Advent Giveaway: Enter to Win a Full Bottle
Niche perfumer Andy Tauer of Swiss brand Tauer Perfumes has been hosting an Advent Giveaway since December 1st, all the way through December 24. It is my utter pleasure today to announce a giveaway for a brand new bottle of your own in any of the scents in the Tauer line as well as a sample of the experimental Eau d'Epices, "fresh from the lab"!
To participate, check today's date on the Advent calendar and Andy's little quiz and leave a comment here on Perfume Shrine to enter the drawing I am hosting, thanks to the generosity of Andy Tauer.
Winner will be announced next week and deadline is December 25th 7AM. Best of luck!!
To participate, check today's date on the Advent calendar and Andy's little quiz and leave a comment here on Perfume Shrine to enter the drawing I am hosting, thanks to the generosity of Andy Tauer.
Winner will be announced next week and deadline is December 25th 7AM. Best of luck!!
Tuesday, December 22, 2009
Musk Series 2: The Natural and Everything about Synthetic Musks
The beauty of musk's scent is that when you smell it on a person's skin, it's hard to tell where one aroma ends and the other begins. "I can feel you on my skin", says one lover to another...The fascinating subject of musk, its origin, its synthetic replication and the multiple variations, surfaces from time to time when we wonder what is hidden in our favourite fragrances ~and not only...
"Not limited to strong perfumes of questionable taste, musk is in fact the basic ingredient of practically all perfumes, from the most expensive and refined French florals to the sleaziest reek of high school hoochies. Everything in your medicine cabinet contains musk: soaps, shampoos, powders, cosmetics, bath oils, even your toothpaste. It is an ingredient in household cleansers, laundry detergents, insect repellents, and almost every other commercial product that requires fragrance - including food. Does the label say "artificially flavored?" Musk is added to fruit flavors, vanilla, chocolates, licorice, hard candy, chewing gum..."[1]
So where do these musks come from and what are synthetic/white musks?
Short History of Musk Use
Musk is the essence coming from a glandular secretion of the male Tibetan musk deer (Moschus moschiferus L), considered an aphrodisiac (as well as a spiritual fragrance in the Muslim world) in the past. It also fixes and balances a composition , refining it in the most plesasurable and sensuous way and allowing floral and resinous ingredients to flourish in it. Its first historical appearence is in the 5th century BC when it is mentioned in the Talmud (Brachot 43.) as an animal-based fragrance. Despite mentions of the supreme smell of the panther, the creature with the most divine scent imagineable according to the ancient Greeks, no reference per se is made in classical antiquity. In the 6th-century Greek explorer Cosmas Indicopleustes references it as a raw material of Indian origin. It took the Arabs and Byzantine perfume makers for it to rise as an aphrodisiac especiall during the height of the Abbasid Empire. The spice and silk route soon took the aromatic essence aboard and the string of languages that reprised the Sanskrit muṣká (denoting testicle, the source of the musk pod) ~via Middle Persian mušk, Late Greek μόσχος (moschos), Late Latin muscus, Middle French musc and all the way into Middle English muske~ is a journey into its aromatic signposts. In the 1970s musks soared: "In response to the "back-to-nature" ethos of the hippie movement, American perfumers on both coasts sought alternatives to traditional French perfumes. Around 1970, both The Body Shop* in Berkeley, CA, and Kiehl's in New York City introduced single-note "essential oil" fragrances". [2]
*In 1987 The Body Shop was taken over by a huge English firm of the same name, taking over the Musk oil that was synthesized in the 1970s and re-introducing it as White Musk, which is comprised of Galaxolide (7,7%), Tonalide (1,6%) a little Cashmeran (0,1%)for a total of 9.4% of white musks.
Origin and Scent of Natural Deer Musk
The musk deer (moschus moschiferus) is a small, inofensive creature living in Pakistan, India, Tibet, China, Siberia and Mongolia and only the mature male can produce musky odour in rutting season. The best quality musk used to come from Tibet (Tonquin/Tonkin musk) and China, while products from India and Siberia were considered of inferior quality. The practice of extracting the musk pods from the deer however is very difficult, as they're close to the testicles of the animal, and becomes fatally cruel (a kilo of musk necessitated the loss of between 30 to 50 deer), rendering the practice nowadays extinct. (According to Christopher Brosius however , there are currently ways of extracting it without harming the deer being examined ,which could bring back the practice of using real musk). The precious pods (worth twice their weight in gold) were dried in the sun, on hot stones, or by putting them in hot oil. The resulting black granular "musk grain" is used in alcoholic dilution, called tincture.
Natural musk in its raw state is pungent, with a strong pervasive urinous (ammoniac) smell that borders on the somewhat fecal and needs storage and considerable dilution for it to unfold all its potential. Still, The cultural perception of musk varies significantly, often swayed by the smeller's twisted impression of what they are smelling, as discussed in our Musk Series Part 1. Most common descriptors state animalic, earthy and woody notes or baby's skin scent, yet when perfumers talk about musk they refer to muscone, the very core of the musk essence devoid of the other ingredients that are included in natural musk (such as ammonia, cholesterol and animalic compounds with resinous odoriferous characteristics).
Other Natural Sources of Musk
The matter is further complicated by the reference of musk in relation to other animals from which glandular substastances are exracted: Ondatra zibethicus, the muskrat (ondantra zibethicus) a rodent, the Musk Duck (Biziura lobata), the muskox, the musk shrew, the musk beetle (Aromia moschata), African Civet (Civettictis civetta), the musk turtle, the alligator of Central America, and often people refer to the animalics of civet cats (civettictis civetta) or castoreum from beavers as animals' musk, further confusing the terms (those last two animals produce animal substances that have different odour profiles). Even a particular type of alligator emits a musky secretion, but it proved to be non-functional for this type of odour aim as it is mainly rosy.
Some plants also have musky smelling compounds, usually of a lactonic macrocyclic nature, such as Angelica archangelica (containing 12-methyl-13-tridecanolide and Exaltolide) or Abelmoschus moschatus (ambrette seeds) produce musky smelling macrocyclic lactonic compounds which enrich fragrant compositions and are a handy if expensive resource for niche and natural perfumers. The former is amply explored in Angeliques sous la Pluie by Jean Claude Ellena for F.Malle. The latter is highlighted in Chanel Les Exclusifs No.18 and Musc Nomade by Annick Goutal. Other sources include musk flower (Mimulus moschatus), and muskwood (Olearia argophylla), to a much smaller degree. Even galbanum, a bitter green grass not usually associated with milky sweet musky smells, contains musk components (14-pentadecanolide and 15-hexadecanolide).
Interestingly, animal derived musks are all ketones, while plant-derived musks are large-ringed lactones.
The Rise of Synthetic Musks: History and Classification
Musk deers became a protected endangered species by the Convention on the International Trade in Endangered Species of Wild Flora and Fauna (CITES) in 1979, rendering natural musk almost obsolete in perfumery (The erratic quantities used by a handful of perfumers come from either old stock ~musk only gains in complexity with storage and doesn't lose its aroma for centuries~ or illegal poaching). Therefore all musk used in perfumery today is synthetic apart from only a handful exceptions which are usually small artisanal perfumers (who are often not at liberty to be open about it due to ethical concerns from consumers).
Although "white musk" is a prevalent epithet used as a blanket-term, the reality is somewhat more complex. The high cost and scarcity of natural musk had always been a concern for the fragrance industry and it was a happy accidental discovery when in 1888, Baur discovered the nitromusks. He had actually been working on explosives, hence the "nitro" prefix, when he discovered that the molecules actually smelled nice: the warm, sweet ambience recalled the scent of muscone. The first nitromusk was thus baptized Musk Bauer in honour of this occurence and a frantic exploration of these aromatic molecules started with the aim of replicating the elusive smell of natural musk. Follow-up nitro-musks, notably musk ketone and musk xylene, are rich, expansive-smelling and very warm; they can be savoured in vintage extraits and colognes, notably in Chanel No.5 (at a staggering 10% concentration) where they shine with their come-hither whisper. Later developments effectuated different kinds of musks.
Synthetic musks can be therefore divided into three major classes — aromatic nitro musks, polycyclic musk compounds, and macrocyclic musk compounds. The first two groups have broad uses in industry ranging from cosmetics to detergents but their continuous presence in human tissue and environmental samples coupled with carcinogenic properties has created concern resulting in a ban or reduction of their use in most countries. Macrocyclic musk compounds are generally considered safer and have replaced the nitro-musks (abandonded since the early 80s) and slowly phasing out the polycyclics. For those concerned with the dangers, WWF has an interesting article downloadable as PDF on this link. (primarily against musk ketone, musk xylene ~both nitromusks~ and polycyclics)
Synthetic musks are essential in modern perfumery forming the base note of most perfume formulae.
However apart from hydrophibic, polycyclics are also lipophilic, as was first discovered in the early 1990s, building up in the bodies of humans and wildlife over time (Daughton 1999).
Traesolide is another synthetic polycyclic musk used as a fragrance ingredient in a variety of consumer products, including soaps, perfumes, and cosmetics and even though Traseolide is not as commonly used as other polycyclics, such as Galaxolide and Tonalide, it has been detected in breast milk, adipose tissue, and blood in humans (Rimkus 1996; TNO 2004; Duedahl-Olesen 2005). They're being steadily replaced by newer molecules.
Ethylene brassylate (or Musk T) is a brassilic ester with floral woody facets, commonly used in cosmetics, because it acts as an odour neutraliser to the other chemicals used, as well as in fine fragrance. Notably it is featured in Dove's Cleansing Towelettes, as well as Olay, Cover Girl, Max Factor and The Body Shop foundations.
Globalide (Habanolide) is a metallic smelling, fresh radiant musk: Smell it in Emporio Armani White For Her, coupled with Helvetolide (please see below), where it forms the signature of nose Alberto Morillas in 2001, giving rise to the term "white musk" ~as opposed to the balmy darkness of the prior nitromusks. Or try it in the ultra-popular aldehydic musk Glow by Jennifer Lopez, accenting the fresh white floral components of the formula; the cooly herbal-soapy Cologne by Mugler and the baby-soft"clean" of Clair de Musc by Serge Lutens. It also balances the sweeter calorific elements in Hypnotic Poison by Christian Dior.
Ambrettolide is lightly sweetly-musky, uniquely vegetal with bordeline floral tones possessing exceptional diffusion which comes through from the very top notes through the base of the fragrance! Although it naturally occurs in ambrette seeds (prefered by niche brands or natural perfumers), it is usually synthesized in the lab. Other popular macrocyclics are Thibetolide (Exaltolide) ~more detectable by women than by men~ and Velvione, the latter from "velvet" and "ketone", referencing the velvety softness resembling older nitromusks and famously comprising almost the entirety of Helmut Lang's Velvione cologne formula.
One interesting case is IFF's Allyl Amyl Glycolate (iso-amyl oxyacetic acid allylester), one of my less prefered musk variants (Chandler Burr describes it as “a combination of the smell of processed pineapple and the tin of the can it comes in”), a clear liquid that can be used in any blend. It possesses sharp green facets with a top resembling the bitter touch of galbanum and a sweet pineapple fruity note. First discovered in 1936, it lagged unnoticed until it was popularised via Italian detergents in the late 1960s. Its use in Camay soap made it familiar and thus it entered fine perfumery: Trace amounts can be found in Alliage by E.Lauder while higher doses can be found in Drakkar Noir by Guy Laroche (1%)and Cool Water by Davidoff (3% which is very high for a powerful synthetic such as this). Trésor, Eternity, and Boss Elements Aqua also use it for its harmonization with the greener notes (lily of the valley, violet leaf).
Newer musks are constantly created, often with imaginative and inspiring names.
Nirvanolide, a chemical produced by Givaudan has a clean sweetly powdery and slightly animalic odour close to the restricted older Musk Ketone. You can smell it in the perfume Forever Elizabeth created by David Apel where it is used in 6.7% concentration. Another chemical with an odour close to Musk Ketone is Muscenone, possessing a very elegant and diffusive musk odour.
Firmenich offers two musk blends, Auratouch 911382 and Auranone 911383. The base of these products contains a captive* musk with a berry top note that performs like a polycyclic musk. Auratouch 911382 is a strong layered musk base with a substantive drydown and contains only triethyl citrate as a solvent. Meanwhile, the base of Auranone 911383—a strong substantive musk base with a delicate floral and somewhat animalic character—has strong ambrette connotations and contains no solvents, or polycyclic or nitro musks.
Meanwhile, the base of Auranone 911383 is a subtle but substantitve assemblage of some of Firmenich's finest musks with ambrette and animalic facets, blended with soft floral notes, devoid of polycyclic or nitro musks. Created around Romandolide, the captive alicyclic is paired with Habanolide, Exaltolide Total, Muscenone and Helvetolide to produce a hard-core musk with traces of sandalwood, amber, violet and powdery notes.
Givaudan has two new synthetic musks: Cosmone and Serenolide. Cosmone, is a single molecule the first C14-macrocyclic musk commercially available, which has a nitro-musk character of great warmth and diffusion which blends well with all kinds of accords. This biodegradable molecule, in addition to Nirvanolide, enlarges Givaudan’s range of environmentally friendly macrocyclic musks and can be smelled in Pi Neo by Givenchy (2008). Serenolide is an elegant white musk with sweet fruity connotations providing warm and soft velvety notes that blend well with all kinds of trendy fruity accords.
Musk R1 (originally from Quest International) is an example of an oxa-macrolide with sensual, powdery musky character.
The fascinating world of musks is far from over: We will return with classifications, descriptions and reviews of musky fragrances on the market!
*Captives are molecules which are patented by companies for their exclusive use for a number of years.
Related reading on Perfume Shrine: Musk Series 1: a Cultural Perception of Musk, Musk Series 3: The Many Permutations of Musk (musk "types")
Ref:
Rowe, David J. (Ed.); Philip Kraft (2004). "Chapter 7. Aroma Chemicals IV: Musks". Chemistry and Technology of Flavours and Fragrances. Blackwell
Charles (Ed.), Sell; Charles Sell (2005).The Chmistry of Fragrances Chapter 4. Ingredients for the Modern Perfumery Industry". Royal Society of Chemistry Publishing.
Robert R. Calkin and J. Stephen Jellinek, Perfumery Practice & Principles
PChirality & Odour PerceptionJohn C. Leffingwell, Ph.D.
Perfume & Flavorist magazine, Musks in Fragrance Blending
Jenny van Veenen Perfume Making
Aromax blog
[1] [2]Epistola S.Fowler: Musk
Painting Lovers by a Tree Mughal, Muhammad Shah period, about 1725 via lokvani.com. Pics via mikndfully.org, Natural Health Crafters, homotography.blogspot.com
"Not limited to strong perfumes of questionable taste, musk is in fact the basic ingredient of practically all perfumes, from the most expensive and refined French florals to the sleaziest reek of high school hoochies. Everything in your medicine cabinet contains musk: soaps, shampoos, powders, cosmetics, bath oils, even your toothpaste. It is an ingredient in household cleansers, laundry detergents, insect repellents, and almost every other commercial product that requires fragrance - including food. Does the label say "artificially flavored?" Musk is added to fruit flavors, vanilla, chocolates, licorice, hard candy, chewing gum..."[1]
So where do these musks come from and what are synthetic/white musks?
Short History of Musk Use
Musk is the essence coming from a glandular secretion of the male Tibetan musk deer (Moschus moschiferus L), considered an aphrodisiac (as well as a spiritual fragrance in the Muslim world) in the past. It also fixes and balances a composition , refining it in the most plesasurable and sensuous way and allowing floral and resinous ingredients to flourish in it. Its first historical appearence is in the 5th century BC when it is mentioned in the Talmud (Brachot 43.) as an animal-based fragrance. Despite mentions of the supreme smell of the panther, the creature with the most divine scent imagineable according to the ancient Greeks, no reference per se is made in classical antiquity. In the 6th-century Greek explorer Cosmas Indicopleustes references it as a raw material of Indian origin. It took the Arabs and Byzantine perfume makers for it to rise as an aphrodisiac especiall during the height of the Abbasid Empire. The spice and silk route soon took the aromatic essence aboard and the string of languages that reprised the Sanskrit muṣká (denoting testicle, the source of the musk pod) ~via Middle Persian mušk, Late Greek μόσχος (moschos), Late Latin muscus, Middle French musc and all the way into Middle English muske~ is a journey into its aromatic signposts. In the 1970s musks soared: "In response to the "back-to-nature" ethos of the hippie movement, American perfumers on both coasts sought alternatives to traditional French perfumes. Around 1970, both The Body Shop* in Berkeley, CA, and Kiehl's in New York City introduced single-note "essential oil" fragrances". [2]
*In 1987 The Body Shop was taken over by a huge English firm of the same name, taking over the Musk oil that was synthesized in the 1970s and re-introducing it as White Musk, which is comprised of Galaxolide (7,7%), Tonalide (1,6%) a little Cashmeran (0,1%)for a total of 9.4% of white musks.
Origin and Scent of Natural Deer Musk
The musk deer (moschus moschiferus) is a small, inofensive creature living in Pakistan, India, Tibet, China, Siberia and Mongolia and only the mature male can produce musky odour in rutting season. The best quality musk used to come from Tibet (Tonquin/Tonkin musk) and China, while products from India and Siberia were considered of inferior quality. The practice of extracting the musk pods from the deer however is very difficult, as they're close to the testicles of the animal, and becomes fatally cruel (a kilo of musk necessitated the loss of between 30 to 50 deer), rendering the practice nowadays extinct. (According to Christopher Brosius however , there are currently ways of extracting it without harming the deer being examined ,which could bring back the practice of using real musk). The precious pods (worth twice their weight in gold) were dried in the sun, on hot stones, or by putting them in hot oil. The resulting black granular "musk grain" is used in alcoholic dilution, called tincture.
Natural musk in its raw state is pungent, with a strong pervasive urinous (ammoniac) smell that borders on the somewhat fecal and needs storage and considerable dilution for it to unfold all its potential. Still, The cultural perception of musk varies significantly, often swayed by the smeller's twisted impression of what they are smelling, as discussed in our Musk Series Part 1. Most common descriptors state animalic, earthy and woody notes or baby's skin scent, yet when perfumers talk about musk they refer to muscone, the very core of the musk essence devoid of the other ingredients that are included in natural musk (such as ammonia, cholesterol and animalic compounds with resinous odoriferous characteristics).
Other Natural Sources of Musk
The matter is further complicated by the reference of musk in relation to other animals from which glandular substastances are exracted: Ondatra zibethicus, the muskrat (ondantra zibethicus) a rodent, the Musk Duck (Biziura lobata), the muskox, the musk shrew, the musk beetle (Aromia moschata), African Civet (Civettictis civetta), the musk turtle, the alligator of Central America, and often people refer to the animalics of civet cats (civettictis civetta) or castoreum from beavers as animals' musk, further confusing the terms (those last two animals produce animal substances that have different odour profiles). Even a particular type of alligator emits a musky secretion, but it proved to be non-functional for this type of odour aim as it is mainly rosy.
Some plants also have musky smelling compounds, usually of a lactonic macrocyclic nature, such as Angelica archangelica (containing 12-methyl-13-tridecanolide and Exaltolide) or Abelmoschus moschatus (ambrette seeds) produce musky smelling macrocyclic lactonic compounds which enrich fragrant compositions and are a handy if expensive resource for niche and natural perfumers. The former is amply explored in Angeliques sous la Pluie by Jean Claude Ellena for F.Malle. The latter is highlighted in Chanel Les Exclusifs No.18 and Musc Nomade by Annick Goutal. Other sources include musk flower (Mimulus moschatus), and muskwood (Olearia argophylla), to a much smaller degree. Even galbanum, a bitter green grass not usually associated with milky sweet musky smells, contains musk components (14-pentadecanolide and 15-hexadecanolide).
Interestingly, animal derived musks are all ketones, while plant-derived musks are large-ringed lactones.
The Rise of Synthetic Musks: History and Classification
Musk deers became a protected endangered species by the Convention on the International Trade in Endangered Species of Wild Flora and Fauna (CITES) in 1979, rendering natural musk almost obsolete in perfumery (The erratic quantities used by a handful of perfumers come from either old stock ~musk only gains in complexity with storage and doesn't lose its aroma for centuries~ or illegal poaching). Therefore all musk used in perfumery today is synthetic apart from only a handful exceptions which are usually small artisanal perfumers (who are often not at liberty to be open about it due to ethical concerns from consumers).
Although "white musk" is a prevalent epithet used as a blanket-term, the reality is somewhat more complex. The high cost and scarcity of natural musk had always been a concern for the fragrance industry and it was a happy accidental discovery when in 1888, Baur discovered the nitromusks. He had actually been working on explosives, hence the "nitro" prefix, when he discovered that the molecules actually smelled nice: the warm, sweet ambience recalled the scent of muscone. The first nitromusk was thus baptized Musk Bauer in honour of this occurence and a frantic exploration of these aromatic molecules started with the aim of replicating the elusive smell of natural musk. Follow-up nitro-musks, notably musk ketone and musk xylene, are rich, expansive-smelling and very warm; they can be savoured in vintage extraits and colognes, notably in Chanel No.5 (at a staggering 10% concentration) where they shine with their come-hither whisper. Later developments effectuated different kinds of musks.
Synthetic musks can be therefore divided into three major classes — aromatic nitro musks, polycyclic musk compounds, and macrocyclic musk compounds. The first two groups have broad uses in industry ranging from cosmetics to detergents but their continuous presence in human tissue and environmental samples coupled with carcinogenic properties has created concern resulting in a ban or reduction of their use in most countries. Macrocyclic musk compounds are generally considered safer and have replaced the nitro-musks (abandonded since the early 80s) and slowly phasing out the polycyclics. For those concerned with the dangers, WWF has an interesting article downloadable as PDF on this link. (primarily against musk ketone, musk xylene ~both nitromusks~ and polycyclics)
Synthetic musks are essential in modern perfumery forming the base note of most perfume formulae.
- Nitro-musks
- Polycyclic musks
However apart from hydrophibic, polycyclics are also lipophilic, as was first discovered in the early 1990s, building up in the bodies of humans and wildlife over time (Daughton 1999).
Traesolide is another synthetic polycyclic musk used as a fragrance ingredient in a variety of consumer products, including soaps, perfumes, and cosmetics and even though Traseolide is not as commonly used as other polycyclics, such as Galaxolide and Tonalide, it has been detected in breast milk, adipose tissue, and blood in humans (Rimkus 1996; TNO 2004; Duedahl-Olesen 2005). They're being steadily replaced by newer molecules.
- Macrocyclic musks
Ethylene brassylate (or Musk T) is a brassilic ester with floral woody facets, commonly used in cosmetics, because it acts as an odour neutraliser to the other chemicals used, as well as in fine fragrance. Notably it is featured in Dove's Cleansing Towelettes, as well as Olay, Cover Girl, Max Factor and The Body Shop foundations.
Globalide (Habanolide) is a metallic smelling, fresh radiant musk: Smell it in Emporio Armani White For Her, coupled with Helvetolide (please see below), where it forms the signature of nose Alberto Morillas in 2001, giving rise to the term "white musk" ~as opposed to the balmy darkness of the prior nitromusks. Or try it in the ultra-popular aldehydic musk Glow by Jennifer Lopez, accenting the fresh white floral components of the formula; the cooly herbal-soapy Cologne by Mugler and the baby-soft"clean" of Clair de Musc by Serge Lutens. It also balances the sweeter calorific elements in Hypnotic Poison by Christian Dior.
Ambrettolide is lightly sweetly-musky, uniquely vegetal with bordeline floral tones possessing exceptional diffusion which comes through from the very top notes through the base of the fragrance! Although it naturally occurs in ambrette seeds (prefered by niche brands or natural perfumers), it is usually synthesized in the lab. Other popular macrocyclics are Thibetolide (Exaltolide) ~more detectable by women than by men~ and Velvione, the latter from "velvet" and "ketone", referencing the velvety softness resembling older nitromusks and famously comprising almost the entirety of Helmut Lang's Velvione cologne formula.
- Alicyclic musks
One interesting case is IFF's Allyl Amyl Glycolate (iso-amyl oxyacetic acid allylester), one of my less prefered musk variants (Chandler Burr describes it as “a combination of the smell of processed pineapple and the tin of the can it comes in”), a clear liquid that can be used in any blend. It possesses sharp green facets with a top resembling the bitter touch of galbanum and a sweet pineapple fruity note. First discovered in 1936, it lagged unnoticed until it was popularised via Italian detergents in the late 1960s. Its use in Camay soap made it familiar and thus it entered fine perfumery: Trace amounts can be found in Alliage by E.Lauder while higher doses can be found in Drakkar Noir by Guy Laroche (1%)and Cool Water by Davidoff (3% which is very high for a powerful synthetic such as this). Trésor, Eternity, and Boss Elements Aqua also use it for its harmonization with the greener notes (lily of the valley, violet leaf).
Newer musks are constantly created, often with imaginative and inspiring names.
Nirvanolide, a chemical produced by Givaudan has a clean sweetly powdery and slightly animalic odour close to the restricted older Musk Ketone. You can smell it in the perfume Forever Elizabeth created by David Apel where it is used in 6.7% concentration. Another chemical with an odour close to Musk Ketone is Muscenone, possessing a very elegant and diffusive musk odour.
Firmenich offers two musk blends, Auratouch 911382 and Auranone 911383. The base of these products contains a captive* musk with a berry top note that performs like a polycyclic musk. Auratouch 911382 is a strong layered musk base with a substantive drydown and contains only triethyl citrate as a solvent. Meanwhile, the base of Auranone 911383—a strong substantive musk base with a delicate floral and somewhat animalic character—has strong ambrette connotations and contains no solvents, or polycyclic or nitro musks.
Meanwhile, the base of Auranone 911383 is a subtle but substantitve assemblage of some of Firmenich's finest musks with ambrette and animalic facets, blended with soft floral notes, devoid of polycyclic or nitro musks. Created around Romandolide, the captive alicyclic is paired with Habanolide, Exaltolide Total, Muscenone and Helvetolide to produce a hard-core musk with traces of sandalwood, amber, violet and powdery notes.
Givaudan has two new synthetic musks: Cosmone and Serenolide. Cosmone, is a single molecule the first C14-macrocyclic musk commercially available, which has a nitro-musk character of great warmth and diffusion which blends well with all kinds of accords. This biodegradable molecule, in addition to Nirvanolide, enlarges Givaudan’s range of environmentally friendly macrocyclic musks and can be smelled in Pi Neo by Givenchy (2008). Serenolide is an elegant white musk with sweet fruity connotations providing warm and soft velvety notes that blend well with all kinds of trendy fruity accords.
Musk R1 (originally from Quest International) is an example of an oxa-macrolide with sensual, powdery musky character.
The fascinating world of musks is far from over: We will return with classifications, descriptions and reviews of musky fragrances on the market!
*Captives are molecules which are patented by companies for their exclusive use for a number of years.
Related reading on Perfume Shrine: Musk Series 1: a Cultural Perception of Musk, Musk Series 3: The Many Permutations of Musk (musk "types")
Ref:
Rowe, David J. (Ed.); Philip Kraft (2004). "Chapter 7. Aroma Chemicals IV: Musks". Chemistry and Technology of Flavours and Fragrances. Blackwell
Charles (Ed.), Sell; Charles Sell (2005).The Chmistry of Fragrances Chapter 4. Ingredients for the Modern Perfumery Industry". Royal Society of Chemistry Publishing.
Robert R. Calkin and J. Stephen Jellinek, Perfumery Practice & Principles
PChirality & Odour PerceptionJohn C. Leffingwell, Ph.D.
Perfume & Flavorist magazine, Musks in Fragrance Blending
Jenny van Veenen Perfume Making
Aromax blog
[1] [2]Epistola S.Fowler: Musk
Painting Lovers by a Tree Mughal, Muhammad Shah period, about 1725 via lokvani.com. Pics via mikndfully.org, Natural Health Crafters, homotography.blogspot.com
Labels:
alicyclic musks,
chemistry,
cosmone,
ethylene brassylate,
fragrance science,
galaxolide,
globalide,
macrocyclic musks,
muscenone,
musk deer,
musk series,
nitromusks,
polycyclic musks
Monday, December 21, 2009
Body Odour Perfume? A Celebrity Challenges Us
Anyone who has read The New York Times articles by Chandler Burr knows that Sarah Jessica Parker is a true fragrance aficionado. Following the author's fascinating book The Perfect Scent confirmed it:
Sarah Jessica likes her own mixture of her beloved Bonne Belle Skin Musk, Comme des Garcons Avignon and Abdul Kareem's musk oil* The effect is positively naughty, as she jokingly intimated, yet for her first foray into fragrance, Coty Inc. decided to start with something decisively tamer and pretty (Lovely), while her second fragrance, Covet, was more unusual, yet still nowhere near what Sarah Jessica truly envisioned, apparently! For her the essential component in a sexy smell is a little...body odour! And that's what the next Sarah Jessica Parker celebrity fragrance under the aegis of trusty partner Coty is going to be after!
Before you frown your pretty little face into a disgusted grimace, let me remind you that there is a primal instinct associated with a little body odour, that fresh sweat can actually smell rather good and that animalics are very popular on these pages, so I am assuming you have cottoned up to the fact that we're interested, by now.
So what does Sarah Jessica Parker's upcoming new fragrance entail? And did she take a page off Matthew McConaughey who likes his body odour and doesn't wear deodorant?
The Sex & The City star told WENN: "I'm working on a new genderless fragrance that's not out yet. I can't even tell you what it's called."It has taken me three years to decide on the scent because I really like B.O. and I think it's sexy. I wanted to figure out a way to make it palatable to everybody."I was like, 'How do you get B.O. in a bottle and make an atomiser of it?' Then it was all about trying to capture the sense of naughtiness in a bottle that it would be good for a man and a woman." [source] In the interim "Parker has been trying out the new scent on journalists and bloggers during her press tour for new movie`Did You Hear About the Morgans?`, in which she stars with British heartthrob Hugh Grant".[source]
Talk about stinky word of mouth! We will see, I guess, although I wouldn't exactly assume the glands of human beings would be squeezed out of their appecrine emitions or she'd target bromhidrosis exactly...That wouldn't be "palatable to everybody". But the desire to be clean yet smell a little skanky, a little 'rolling out of bed' ~that bed not exactly equipped with chastity belts~ seems like a sexy idea!
*[The latter wasn't revealed via Burr at all; in fact this is journalistic conjecture on our part, since she has been great friends with Narciso Rodriguez and a fan of his perfume ~Lovely was fashioned after Narciso, after all~ and Rodriguez had been inspired for his first fragrance by a musk oil that his muse Caroline Bessette was buying for the three of them in New York City, which was revealed to be Abdul Kareem's posthumously.]
Black & white photograph of Sarah Jessica Parker in a bikini via msanto/photobucket.
Sarah Jessica likes her own mixture of her beloved Bonne Belle Skin Musk, Comme des Garcons Avignon and Abdul Kareem's musk oil* The effect is positively naughty, as she jokingly intimated, yet for her first foray into fragrance, Coty Inc. decided to start with something decisively tamer and pretty (Lovely), while her second fragrance, Covet, was more unusual, yet still nowhere near what Sarah Jessica truly envisioned, apparently! For her the essential component in a sexy smell is a little...body odour! And that's what the next Sarah Jessica Parker celebrity fragrance under the aegis of trusty partner Coty is going to be after!
Before you frown your pretty little face into a disgusted grimace, let me remind you that there is a primal instinct associated with a little body odour, that fresh sweat can actually smell rather good and that animalics are very popular on these pages, so I am assuming you have cottoned up to the fact that we're interested, by now.
So what does Sarah Jessica Parker's upcoming new fragrance entail? And did she take a page off Matthew McConaughey who likes his body odour and doesn't wear deodorant?
The Sex & The City star told WENN: "I'm working on a new genderless fragrance that's not out yet. I can't even tell you what it's called."It has taken me three years to decide on the scent because I really like B.O. and I think it's sexy. I wanted to figure out a way to make it palatable to everybody."I was like, 'How do you get B.O. in a bottle and make an atomiser of it?' Then it was all about trying to capture the sense of naughtiness in a bottle that it would be good for a man and a woman." [source] In the interim "Parker has been trying out the new scent on journalists and bloggers during her press tour for new movie`Did You Hear About the Morgans?`, in which she stars with British heartthrob Hugh Grant".[source]
Talk about stinky word of mouth! We will see, I guess, although I wouldn't exactly assume the glands of human beings would be squeezed out of their appecrine emitions or she'd target bromhidrosis exactly...That wouldn't be "palatable to everybody". But the desire to be clean yet smell a little skanky, a little 'rolling out of bed' ~that bed not exactly equipped with chastity belts~ seems like a sexy idea!
*[The latter wasn't revealed via Burr at all; in fact this is journalistic conjecture on our part, since she has been great friends with Narciso Rodriguez and a fan of his perfume ~Lovely was fashioned after Narciso, after all~ and Rodriguez had been inspired for his first fragrance by a musk oil that his muse Caroline Bessette was buying for the three of them in New York City, which was revealed to be Abdul Kareem's posthumously.]
Black & white photograph of Sarah Jessica Parker in a bikini via msanto/photobucket.
Sunday, December 20, 2009
Dior J'Adore: fragrance review & J'Adore Versions (L'Eau Cologne Florale, J'Adore L'Absolut, J'Adore L'Or) on the Market
Accessing the popularity stakes and artistic success of a bestseller is never an easy thing. Perhaps it's the competitors who speak most frankly about its cachet: As Thierry Wasser, head perfumer at Guerlain at the moment, revealed in an interview on Swiss television, "Every one of us wants to make the next J'Adore!"
The aphorism ~on a fragrance with a name that means "I LOVE it!"~ was meant to convey the ubiquitousness of the scent, its staggering approval by consumers from young to old. Such ubiquitousness in fact that its commercial's televised air-time 10 years after its introduction in 1999 has raised questions on a popular perfume forum about the reasons behind it!
The makings of a best-seller
You see, gone are the days of Chanel No.5 when commercials were running for the same scent for decades: Today the fast-paced churning out of fragrances means that the bombarding with advertising images changes dramatically from season to season with the latest and the glossiest catching page after page and air-minute after air-minute in an attempt to lure us into the Great New Thing. Alas, so very few times they deliver. Yet there is no question about Christian Dior's fragrance enduring presence in both the media and ~what's more important~ on the dressers and the bodies of countless women on the planet: Yes, by that token Dior's J'Adore is a modern classic!
Stating such a claim makes eyebrows raise on perfumistas' foreheads, accustomed as they are to the exclusive, the arcane, the unattainable or alternatively the vintage, the classic and the ultra-rare. But the beauty of perfumery is that one doesn't need to go up digging for Alexander the Great's grave (a task several worthy people have been unsuccessful at, its location forever unknown); one can find a good thing even almost on their doorstep (or in this case their local Sephora) and like Alexander's golden locks it is gilded and shiny with its "giraffe women" necklaces around the stem of the bottle and screaming with every drop of its jus "I'm covetable". A gorgeous face in Charlize Theron's shoes strutting her statuesque shape is challenging ~but also promising to~ every woman to become a living goddess! "Woman is an idol, and must be adorned to be adored," wrote Charles Baudelaire and Dior was quick to snatch the immortal line for their own purposes.
Pinkification: more to it than meets the eye
J'Adore (pronounced Za-DORH) clout however took an unexpected and fascinating path to form. Back in 1999 the fruity floral vogue was just catching on, as consumers tired of the acquatics and ozonics of the 90s and of the realisation that the dot com prodigies were not something to sustain the economy as foretold were searching for a little girliness, a little pinkiness ~even a reversion to the mental age of Barbie some would say! (and who can blame them in retrospect?) A recent article at The Guardian talks about the pinkification of our culture where beauty "gurus" emote in exalted girly-tones that could shutter crystal and have you screaming up the walls with devious and not so devious plans on assassinating the perpatrators of those auditory crimes. (parodies abound, so not all hope is foresaken). The cultural background of this phenomenon is vaster than the scope of those pages, yet a fragrance such as J'Adore managed to come aboard at the exact time when the wave of girlishness was gaining momentum. And we have to grugingly admit: Among all the girly fruity florals, J'Adore actually manages to inject a little womanly touch there too: It's not completely air-headed!
In Dior's portfolio it is something of a chasm, a no man's land where the classics (Miss Dior, Diorissimo, Eau Fraiche, Diorama, Diorling, Diorella, Dior-Dior and Dioressence) along with the established (Dune, Poison and some of the latter's flankers) veered off in favour of the modern specimens which are targeted to a different audience (Addict, Addict Shine, Forever and Ever etc.).
In a way J'Adore was the catalyst which ushered the pounding thumb of fruity florals not only chez Dior but along the widths and the breadths of the feminine fragrance market. Calice Becker, the perfumer behind J'Adore, is famous for her symphonic yet non-obese florals. Essentially linear, J'Adore begins and ends on a complicated yet quite fresh bouquet that oscillates between the velvety sheen of orchids and champaca with their sensuous air and the fruitier elements of rich plum, sprinkled with droplets of sweet citrus fruit, hints of greenery and a soupçon of violet & rose coquetry (ionones). The whole is underscored by cassis (a synthetic base very popular in the 80s, also used in Poême with which it shares an indefiniable vibe) with subtle woods. The longer the perfume stays on the more it projects that latter element. The eau de parfum's tenacity is indeed phenomenal and it manages to radiate even from the blotter for a while.
And when all is said and done, it smells nice. I wouldn't trail the Himalayan Route for it like I would with other fragrances and it's a little too sweet and ubiquitous for my personal tastes, but it's a round, feminine scent that attracts compliments. Think about how women have passed you by at the street, your nostrils quivered at their scent and you almost murmured j'adore....
Notes for Christian Dior J'Adore: Mandarin, champaca flowers, ivy, African orchid, rose, violet, Damascus plum, amaranth wood, blackberry musk
Dior J'Adore Special Editions and Flankers
The face of J'adore was initially Esthonian beauty Carmen Kaas, but it was Hollywood star Charlize Theron who really "clicked" and gave J'Adore an immense visual advantage.
J'Adore is available at every Dior counter everywhere, available in the following versions/flankers:
1) the original J'Adore Eau de Parfum concentration (1999) in the golden toned bottle depicted in the ads and reviewed above
2) the lighter and less plummy J'Adore Eau de Toilette (2002) in the silvery-toned design (pictured on the right). In 2011 the eau de toilette concentration was re-orchestrated (due to changes in perfumery regulations) by Francois Demachy, giving it a sweeter and fresher appeal, and repackaged in the gold scheme packaging and presentation, only differentiated from the EDP by the notification on the packaging.
3) the magnificent, limited (and costlier) edition of J'Adore L'Absolu (2007) a delightfully intense version of the classic favorite with Turkish rose, tuberose, and jasmine combine to make a truly pretty floral" (Eau de Parfum Absolute, created by Francois Demachy). A superior version of the formula, developed by Francois Demachy with premium floral essences.
4) the J'Adore L' Eau Cologne Florale 2009 (the bottle is in golden tones, but a little more slender), which reprises the floral theme with touches of lemony magnolia to render a very current modernisation of the brand. The range is complimented with ancilary body products and is often augmented with special editions that reprise the design of the bottle.
5) J'Adore L'Or is a essence de parfum edition launched in 2010 with the neck of the bottle in thin gold threads and the same amphora style body, available only in 40ml. It's an amped up and more expensive version of the eau de parfum with sweeter and headier florals and a more lasting and very perceptible vanilla base.
6) A limited edition from 2007 highlighting the jasmine note is J'Adore Le Jasmin, available in 100ml of alcohol-free eau de toilette for the summer. Longer, leaner amphora bottle, but otherwise same, with a box reading "summer fragrance" underneath the name. Not to be confused with the 2004 summer fragrance, which is encased in the familiar bottle that holds EDT or EDP, with the only difference being marked in the box ('summer fragrance').
The following limited editions are only different in the bottle presentation or visuals and do not bear a difference in the scent itself.
Special limited "anniversary" editions of J'Adore en Or come from 2004 and 2009 (for the 5 and 10 years of the market respectively); the former with curved drawn "lines" on the upper body of the matte gold bottle, the latter with a golden medallion with the initials CD hanging on a thread on the transparent glass familiar amphora-shaped body. A shimmery version called J'Adore Divinement d'Or (Gold Supreme) was issued in 2006 with gold shimmer suspended in the juice.
Photo by JeffWestboorke, pics via it's all about life blog
The aphorism ~on a fragrance with a name that means "I LOVE it!"~ was meant to convey the ubiquitousness of the scent, its staggering approval by consumers from young to old. Such ubiquitousness in fact that its commercial's televised air-time 10 years after its introduction in 1999 has raised questions on a popular perfume forum about the reasons behind it!
The makings of a best-seller
You see, gone are the days of Chanel No.5 when commercials were running for the same scent for decades: Today the fast-paced churning out of fragrances means that the bombarding with advertising images changes dramatically from season to season with the latest and the glossiest catching page after page and air-minute after air-minute in an attempt to lure us into the Great New Thing. Alas, so very few times they deliver. Yet there is no question about Christian Dior's fragrance enduring presence in both the media and ~what's more important~ on the dressers and the bodies of countless women on the planet: Yes, by that token Dior's J'Adore is a modern classic!
Stating such a claim makes eyebrows raise on perfumistas' foreheads, accustomed as they are to the exclusive, the arcane, the unattainable or alternatively the vintage, the classic and the ultra-rare. But the beauty of perfumery is that one doesn't need to go up digging for Alexander the Great's grave (a task several worthy people have been unsuccessful at, its location forever unknown); one can find a good thing even almost on their doorstep (or in this case their local Sephora) and like Alexander's golden locks it is gilded and shiny with its "giraffe women" necklaces around the stem of the bottle and screaming with every drop of its jus "I'm covetable". A gorgeous face in Charlize Theron's shoes strutting her statuesque shape is challenging ~but also promising to~ every woman to become a living goddess! "Woman is an idol, and must be adorned to be adored," wrote Charles Baudelaire and Dior was quick to snatch the immortal line for their own purposes.
Pinkification: more to it than meets the eye
J'Adore (pronounced Za-DORH) clout however took an unexpected and fascinating path to form. Back in 1999 the fruity floral vogue was just catching on, as consumers tired of the acquatics and ozonics of the 90s and of the realisation that the dot com prodigies were not something to sustain the economy as foretold were searching for a little girliness, a little pinkiness ~even a reversion to the mental age of Barbie some would say! (and who can blame them in retrospect?) A recent article at The Guardian talks about the pinkification of our culture where beauty "gurus" emote in exalted girly-tones that could shutter crystal and have you screaming up the walls with devious and not so devious plans on assassinating the perpatrators of those auditory crimes. (parodies abound, so not all hope is foresaken). The cultural background of this phenomenon is vaster than the scope of those pages, yet a fragrance such as J'Adore managed to come aboard at the exact time when the wave of girlishness was gaining momentum. And we have to grugingly admit: Among all the girly fruity florals, J'Adore actually manages to inject a little womanly touch there too: It's not completely air-headed!
In Dior's portfolio it is something of a chasm, a no man's land where the classics (Miss Dior, Diorissimo, Eau Fraiche, Diorama, Diorling, Diorella, Dior-Dior and Dioressence) along with the established (Dune, Poison and some of the latter's flankers) veered off in favour of the modern specimens which are targeted to a different audience (Addict, Addict Shine, Forever and Ever etc.).
In a way J'Adore was the catalyst which ushered the pounding thumb of fruity florals not only chez Dior but along the widths and the breadths of the feminine fragrance market. Calice Becker, the perfumer behind J'Adore, is famous for her symphonic yet non-obese florals. Essentially linear, J'Adore begins and ends on a complicated yet quite fresh bouquet that oscillates between the velvety sheen of orchids and champaca with their sensuous air and the fruitier elements of rich plum, sprinkled with droplets of sweet citrus fruit, hints of greenery and a soupçon of violet & rose coquetry (ionones). The whole is underscored by cassis (a synthetic base very popular in the 80s, also used in Poême with which it shares an indefiniable vibe) with subtle woods. The longer the perfume stays on the more it projects that latter element. The eau de parfum's tenacity is indeed phenomenal and it manages to radiate even from the blotter for a while.
And when all is said and done, it smells nice. I wouldn't trail the Himalayan Route for it like I would with other fragrances and it's a little too sweet and ubiquitous for my personal tastes, but it's a round, feminine scent that attracts compliments. Think about how women have passed you by at the street, your nostrils quivered at their scent and you almost murmured j'adore....
Notes for Christian Dior J'Adore: Mandarin, champaca flowers, ivy, African orchid, rose, violet, Damascus plum, amaranth wood, blackberry musk
Dior J'Adore Special Editions and Flankers
The face of J'adore was initially Esthonian beauty Carmen Kaas, but it was Hollywood star Charlize Theron who really "clicked" and gave J'Adore an immense visual advantage.
J'Adore is available at every Dior counter everywhere, available in the following versions/flankers:
1) the original J'Adore Eau de Parfum concentration (1999) in the golden toned bottle depicted in the ads and reviewed above
2) the lighter and less plummy J'Adore Eau de Toilette (2002) in the silvery-toned design (pictured on the right). In 2011 the eau de toilette concentration was re-orchestrated (due to changes in perfumery regulations) by Francois Demachy, giving it a sweeter and fresher appeal, and repackaged in the gold scheme packaging and presentation, only differentiated from the EDP by the notification on the packaging.
3) the magnificent, limited (and costlier) edition of J'Adore L'Absolu (2007) a delightfully intense version of the classic favorite with Turkish rose, tuberose, and jasmine combine to make a truly pretty floral" (Eau de Parfum Absolute, created by Francois Demachy). A superior version of the formula, developed by Francois Demachy with premium floral essences.
4) the J'Adore L' Eau Cologne Florale 2009 (the bottle is in golden tones, but a little more slender), which reprises the floral theme with touches of lemony magnolia to render a very current modernisation of the brand. The range is complimented with ancilary body products and is often augmented with special editions that reprise the design of the bottle.
5) J'Adore L'Or is a essence de parfum edition launched in 2010 with the neck of the bottle in thin gold threads and the same amphora style body, available only in 40ml. It's an amped up and more expensive version of the eau de parfum with sweeter and headier florals and a more lasting and very perceptible vanilla base.
6) A limited edition from 2007 highlighting the jasmine note is J'Adore Le Jasmin, available in 100ml of alcohol-free eau de toilette for the summer. Longer, leaner amphora bottle, but otherwise same, with a box reading "summer fragrance" underneath the name. Not to be confused with the 2004 summer fragrance, which is encased in the familiar bottle that holds EDT or EDP, with the only difference being marked in the box ('summer fragrance').
The following limited editions are only different in the bottle presentation or visuals and do not bear a difference in the scent itself.
Special limited "anniversary" editions of J'Adore en Or come from 2004 and 2009 (for the 5 and 10 years of the market respectively); the former with curved drawn "lines" on the upper body of the matte gold bottle, the latter with a golden medallion with the initials CD hanging on a thread on the transparent glass familiar amphora-shaped body. A shimmery version called J'Adore Divinement d'Or (Gold Supreme) was issued in 2006 with gold shimmer suspended in the juice.
Photo by JeffWestboorke, pics via it's all about life blog
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