Showing posts with label quinoline. Show all posts
Showing posts with label quinoline. Show all posts

Wednesday, February 20, 2008

Lament for a Fragrance in Sepia ~Cabochard by Gres: fragrance review

“Headstrong” or “stubborn” is not the first thing that comes to mind when I contemplate on my mother’s personality. Yet it was the formidable, petulant perfume thus named, Cabochard, that had won her heart and ~along with Dioressence~ became her insignia. The Grecian-inspired fluted designs of Madame Grès which were cut directly on the body would have suited the Dorian drama of her beauty. Her dreamy flair for romanticism however betrayed appearences and made a fascinating juxtaposition with her bombshell fragrances. Thus the merest whiff out of her now almost empty bottle never fails to bring back poignant memories of my childhood with a Proustian rush. Talking about it dews my eyes like writing the obituary on an era: trying to recapture those sepia memories like a faded vignette is doomed to fail due to the fragrance being irrecovably changed.

Cabochard comes from the old French word “caboche”, meaning "headstrong" or "self-willed", according to the Petit Robert dictionary. It was Alix Grès, neé Germaine Emilie Krebs and formally trained as a sculptress, who opted for it, to accompany the independent nature of her couture. Alix Barton was her first business pseydonum. But she later took her husband’s ~Serge Czerefkov, a Russian painter ~ first name and with a partial anagram settled on Grès, opening la maison Grès in 1942, amidst the German occupation of Paris. Soon she was dressing everyone, from the Dutchess of Windsor to Marlen Dietrich and Greta Garbo.

The story of creating Cabochard
The credit into making Cabochard a success is attributed to Guy Leyssène, who met Madame Grès at a dinner part two years prior to the perfume’s launch, per Michael Edwards. It was Guy's suggestion that she should issue one because it was a profitable enterprise which all the other fashion designers of the times had embarked on. It took only a month for Grès to ask him to help her create her own perfume. {interestingly, according to history of fashion.com the first perfume was called Muse in 1946}. However, nothing is as simple as it might look. "Cabochard is a miracle of complexity […] the secret life of a Parisian woman with no age and no illusions" wrote Luca Turin about its scent in 1994 and its story is just as complex.

The perfume that was in works was a composition by legendary perfumer Guy Robert, called Chouda. Robert was young and under the guidance of mentor Andrée Castanié, then editor of L'Officiel de la Mode et de la Couture, had been introduced to Mme Grès in 1956. But it took a trip to India, the land of exoticism, which prompted Alix Grès to further her plans on the house’s fragrance. The visit had begun innocuously, invited by the Ford Foundation to assess Indian brocades. It was there that Alix Grès discovered water hyacinth: a flower she became enraptured with. It has a sweet odour, rich like tuberose, yet with a fresher top and slightly warmer. The experimentation of Guy Robert yeilded rich fruits: Alix loved it, however Chouda was almost exclusively used by her (only five litres of Chouda were ever made) as it was too flowery for the tastes of the 50s which veered towards classic chypres. She launched another fragrance under the pressure of public input: the mod of what was to become Cabochard, made by Bernand Chant of IFF, was received much more favourably and thus the plan to push Chouda was ultimately abandoned, although the two were issued almost simultaneously in 1959. It comes as a surprise that there were focus groups even back then, but it is a fact that puts things into perspective: public reception is (and will always be) the moniker of how things work in a sector that, although hinges on art, is also largely a business.


The story of the bottle for Cabochard, as well as Chouda, is also extraordinary in that it was the already made and discarded stock of Guighard, a small glass manufacturer later acquired by Pochet. They had made the bottles for another company who never bought them and in order to save costs, Grès bought all 500 of them for both perfumes. The difference was the little bow that adorned the pharmaceutical stopper: grey for Cabochard, green for Chouda. The Cabochard success (it sold 250 bottles in the first week of its launch alone!) secured numerous backorders to the glass manufacturer. In a way, the commercial success owed to the enthusiasm with which it was promoted by a commission salesman formerly working for Piguet (whose biggest seller at the time was Bandit). According to Leyssène the demand was so pressing the sales were doubled each year for the following ten years!

Scent Considerations: A Leathery Chypre Marvel
Cabochard utilised the same aromachemical with Bandit: isobutyl quinoline, a harsh green and pungent, dry leather aroma, yet fanning expensive, precious, sweet flowers over it. Inspired by the archetype it muted the smokiness until the drydown. Cabochard offers a capricious bitter orange opening instead, with the illusion of wading through wild bracken catching a distant whiff of clove and hairspray. The crackling leather, powdery afterfeel of face cosmetics was sustained for hours on skin, emitting grace and confidence in a similar manner to Chanel’s Cuir de Russie, although with rather more sweetness and less birch. To Gres it recalled a walk along a deserted Indian beach:
“the crispness of the early morning air, the warmth of sandalwood, a hint of far-off flowers, and the dry caress of sea breezes”.

The parfum sitting on the dresser of my mother ever since I can remember was so warm and rich than mere drops were enough to scent her hair and garments, retaining the essence of who she was into my heart of hearts. The eau de parfum in older versions is also exceptionally good, while the eau de toilette has a lighter but sharper quality.

The difference between the vintage and the recent re-editions can be traced back to 1984 when Beecham Cosmetics acquired British American Cosmetics, who had bought the Grès brand in the interim after Alix closed the couture house. To celebrate Cabochard's twenty-fifth anniversary, they changed the grey velvet bow into frosted glass, encased the bottle in a black instead of a black-and-white one and brightened the citrus top while also restraining the animalic accord. The 40th anniversary of Cabochard was celebrated in 1999 with a Bacarrat crystal flacon, designed by Serge Mansau and what seems yet another re-formulation which finally put the tombstone on one of the best in my opinion perfumes of the 20th century.

Official notes for Madame Gres Cabochard:
Top: aldehydes, bergamot, mandarin, galbanum, spice
Heart: jasmine, rosa damscena, geranium, ylang-ylang, iris
Base: patchouli, leather, vetiver, castoreum, oakmoss, tobacco, musk, labdanum, sandalwood

Pic of bottle from official Gres site

Friday, December 7, 2007

Leather Series 3: Production

Rendering a leather note in perfumery is a challenge for the perfumer who must coax this difficult and cult note into submission to make it sing with the rest of the composition. Production relies on two different courses: naturally derived and synthesized in a lab. Both account for a potent aroma of smoky and alteratively drier or sweeter notes, characteristic of the cuir family.

Let’s see what is actually used.

The naturals:

Birch: Betula Alba, the tree known as birch, owes its name to the Latin verb batuere meaning to strike. It is no coincidence that the branches of birch have been used for corporal punishment. Traditionally used in tanneries in Russia, Finland and Northern Europe in general, its bark produces birch tar and resin, an intensely wintergreen and tar-like odour, which has been used in Cuir de Russie type of scents in the distant past. The oil is widely used in suede and leather tannery in Russia and the essence obtained from birch buds is used for hair tonics and some cosmetic products.

Juniper and cade oil:
Juniper trees produce dark viscuous oil (cade) upon getting burned which possesses a smoky aroma that reminds one of campfires in the forests. Also used in Cuir de Russie type of scents in the past along with birch. It additionally has an anti-mould property which explains why it is a prime material for the binding of books, surely prone to decay and deterioration otherwise.

Styrax: Liquidambar Styraciflua and Liquidambar Orientalis trees are used for their excretion of the sapwood obtained by pounding the bark of both varieties. L. Styraciflua comes from the Americas (in particular Honduras, Guatemala and Mexico), while L.Orientalis comes from Asia Minor. The essence used in perfumery to give a leather undertone comes from the Honduras and is purified with volatile solvents or through vacuum distillation.
Styrax notes are usually sweeter than those of birch when used for leathery notes.

Cassie: The bark of cassie, a tree that belongs to the family of mimosa, and the absolute from the flowers are also used for giving a deep, intense leather note in some perfumes based on natural essences.

Castoreum: The secretion from the glands of beavers from Russia and Canada is a very intense, repulsive odour that when highly diluted can provide a leathery scent to fine perfumery. A by-product of the fur industry, it has been prized in perfumery for its tremendous fixative powers and its deeply animalic edge with a dry quality that smells like real leather.

Another natural essence that can produce a leather note although not usually used as such is Myrtle. Because of its camphoreous, green, rather than pungent leathery aroma, it is not the preferred choice for rendering a leather note in perfumes; although it is used in tanneries for the curing of hides.

Last but not least, cistus labdanum can provide a leathery backdrop- in cases where a more smokey/ ambery note is required ~such as in Caron Tabac Blond, Serge Lutens Cuir Mauresque and Ava Luxe Madame X {click for review}.

It is important to note that natural perfumers can render leather notes in their perfumes through the combined use of different essences such as black tea, patchouli or tobacco in addition to the above; sometimes opting for ethically avoiding animal products (castoreum) altogether.


The synthetics:

The major revolution in the production of leathery notes in perfumery came in the 1880s with the apparition of quinolines, a family of aromachemicals with a pungent leather and smoke odour that was used in the production of the modern Cuir de Russie scents appearing at the beginning of the 20th century such as Chanel’s (1924) as well as in Caron’s Tabac Blond (1919), Lanvin’s Scandal (1933) and, most importantly, Piguet’s Bandit (1944).

The chemical name of the ingredient primarily used from the quinolines groups is 4-(2-methylpropyl) quinoline, commonly referred to as isobutyl quinoline. A colourless to pale yellow liquid, used in a dilution of 1.00 % solution or less, it possesses a fiercely potent odour profile described as earthy, rooty, and nutty, echoing certain facets of oakmoss and vetiver and blending very well with both. Isobutyl quinoline also has ambery, woody, tobacco-like undertones: a really rich aromachemical! Its character can be very well perceived in the above scents as well as Cabochard by Gres.

Another synthesized note is the suede accord: a much subtler, more velours deep feel in the realm of leather notes. Less aggressive, suede notes are created in the laboratory for modern fine perfumes such as Lutens’ Daim Blond and Donna Karan. The origins hinge on muscone in the past or a complex tactile evocation of suede through a secret formula for more recent examples.

To a lesser degree the safraleine aromachemical can add a leathery tinge to perfumes. Evident in isolate of saffron, safraleine has an interesting smell ~ a combination of shoe polish/black cherry/air conditioning refrigerating fluid.

Aldehydes and especially C10, C11 and C12 are also used in addition to other ingredients in leathery perfumes to round out the composition and make it smooth.

Last but not least, in an effort to find materials that would enhance or augment leather tones and provide a cheaper and more stable alternative to animal-derived castoreum for rendering leather notes, the US Patent 4528124 (Jul, 1985 Sturm et al.252/522) has been proposed as a solution. The compound having the structure ##STR2## is a known compound disclosed at Chemical Abstracts Volume 99, Monograph 139339e. As I haven't smelled this secret ingredient I cannot report back on its effect, but it worth mentioning.

The search for materials which can provide a more refined leathery and castoreum aroma profile apparently continues.



Next instalment will focus on a scent fit for kings.

Pic of birch forest, Birch Hill Fairbanks in Alaska by Jeff Breu courtesy of Google images

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