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Although perfume lockets and scent-filled jewelry is making a resurgence among collectors and craftsmen and craftswomen who are very active online with dedicated eshops or boutiques on sites such as Etsy or Ebay, the lesser known tradition of perfumed buttons is one that has been passed by. It's also something which can be fairly easily replicated by anyone as a flirting trick, as it requires simply a few easily found buttons and some perfume at hand (and I'm sure that readers of this site are amply decked with the latter!).
Among functional little objects, such as the humble button, the Victorian and Edwardian women and craftsmen knew no boundaries in their imaginative prowess into creating patterns and styles that would both visually please (such as the portrait buttons, jet with lustre or the ones featuring French enamel on the high end or the calico ones on the lower end) or occasionally serve other, less obvious purposes. Victorian "perfume buttons" specifically involved fabric-covered buttons which were including pieces of velvet in their sewing pattern which were then dabbed with a woman's favorite perfume. This way the thickish fabric retained the scent, subtle but lingering and creating a hint of a fragrant wake.
The tradition took an especially poignant and romantic purpose when these perfume buttons were sewn under the lapel of a beau's jacket going off to fight on some far away land in dangerous trenches or in the American Civil War, or -less riskily- when he was traveling, so that the fragrance wafting from the chest upwards would remind him of the woman he had left behind. Since both women and men shared their fragrant innocuous blends that invariably revolved around violets, rose, lavender and such ~if we refer to polite society and not the demi-monde who favored heavier and more animalic-smelling scents ~ there was no social faux pas in having a man waft a woman's scent.
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Another reason for the popularity of Victorian perfume buttons had a twofold explanation. The Victorians had a romanticized and slightly puritanical vision of the body, as an abode and sanctum, where no scent should actually touch the skin, therefore favoring the scenting of accessories such as handkerchieves, fans and the good ol' gloves (for more on that see PerfumeShrine's article on Scented Gloves and their History). Since some of the scented essences involved oily carriers, preceding as they did the modern era of ethanol dilution of powerful synthetics that bypass the problem of staining, the medium of carrying the perfume was important to be stain-proof. Dark velvet wasn't exactly immune to oily stains, but they didn't show as they would on the satiny silk and wool fabrics of dresses. Therefore a sort of decorative brass buttons with velvet fabric inside were created to accommodate and a vogue for long "necklaces" or decorative "edges" of buttons emerged. There were even sometimes crafted into pieces of jewelry, such as bracelets, necklaces or earrings, some of which survive in modern re-interpretations for the antique and vintage lover.
A tradition that should see a rebirth, if you ask me!
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