The things one comes across....In Wikipedia, the fast-food of knowledge and the road to quick access to most about anything, there is an article on Celebrity Endorsed Perfumes: in list form, no less!
The list is not exhaustive, but it's comprehensive enough and categorised according to occupation, which comes very handy when you're frantically searching just what perfume was graced by the mug of your favourite actor/singer/socialite/whatever.
From Miss You Nights and Devil Woman by Cliff Richards (yes, who would have thought?) to Moi by Miss Piggy (now, there's a face to launch a thousand ships!) and Mojo by Austin Powers, here is the list of famous faces which have fronted perfumes. Click on this link!